ISSN:
0887-624X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The design of spiroorthocarbonate monomers (SOCs) and related structures is discussed with the aim of maximizing monomer polymerizability in the absence of undesirable byproducts. The successful syntheses of N,S-analogs of aryl- and alkaryl-SOCs are reported; these are monomers of structure where P and Q are —O— and —OC(CH3)2-, mp 156-158°C; and P and Q are —OCH2— and —OCH2—, mp 148-150°C. As is indicated by infrared spectra, the polymerization of both monomers is initiated by boron trifluoride etherate. © 1993 John Wiley & Sons, Inc.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pola.1993.080310704
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