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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 195-201 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Using low conversion bulk copolymerization experimental data and the apparent rate constant model, the monomer chain cross-transfer rate constants and the cross-termination coefficient were evaluated. It was found that the dependence of the cross-termination coefficient on composition is a function of initiator efficiency and that monomer chain cross-transfer rate constant are relevant for the theoretical estimation of the molecular weights and molecular weight distributions.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Journal of Vinyl and Additive Technology 14 (1992), S. 202-206 
    ISSN: 0193-7197
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this work PVC plastisol rotational molding formulations were characterized as a function of processing conditions. Temperature sweep runs in the 60 to 220°C range suggest the presence of different stages in the solidification process, marked by the crossover of storage (G′) and loss (G″) moduli. Viscoelastic properties as a function of time were measured at different processing temperatures (in the 80 to 220°C range). Ultimate strength, ultimate elongation, and solvent resistance of the formulations after processing were also measured to evaluate performance.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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