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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Munksgaard International Publishers
    Indoor air 9 (1999), S. 0 
    ISSN: 1600-0668
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Medicine
    Notes: Abstract A simple test chamber method to quantify adsorption and desorption of organic compounds on material surfaces is described. Important environmental parameters such as temperature, relative humidity and air velocity were varied and controlled independently around typical indoor values. Experiments were performed with α-pinene and toluene in concentrations of 160-300 μg/m3. The measurements show adsorption on and desorption from wool carpet, nylon carpet, polyvinyl chloride (PVC) floor coverings, cotton curtain material and the empty chamber. The ranking of the materials, with respect to their sorption capacity, is as mentioned above. The adsorption of α-pinene was higher than the adsorption of toluene for all the materials. Air velocity was not found to influence the sorption of α-pinene and toluene on wool carpet, tested with air velocities at 0, 10 and 20 cm/s. The experiments were carried out during both the adsorption and the desorption phase. The uncertainty of the experiments was lowest during the desorption phase. Based on the results obtained, it can be recommended that sorption experiments should be performed as desorption phase experiments. A one-sink model, based on the Langmuir adsorption isotherm, appears adequate to describe the results.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1600-0668
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Medicine
    Notes: Abstract A sink-diffusion model to describe the interaction between material surfaces and volatile organic compounds (VOCs) in indoor air has been introduced. The model is based on adsorption/desorption on the material surfaces and diffusion into the materials. Test chamber experiments with exposure of nylon carpet and polyvinyl chloride (PVC) covering against α-pinene and toluene were used to validate the model and to make comparisons with a sink model based on the Langmuir adsorption isotherm. The results showed that the sink-diffusion model gave a better description of the desorption curve than the Langmuir model. The model predictions improved with increasing sorption effect. The Langmuir model gave good predictions of relative weak sorption effects, whereas the sink-diffusion model improved the predictions for stronger sorption effects. In this case, nylon carpet showed substantial stronger sorption than PVC covering and α-pinene showed stronger sorption than toluene. Controlled field experiments with combinations of building materials and a mixture of VOCs, encountered in real indoor environments, are needed to further validate the sink-diffusion model.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2017-12-01
    Print ISSN: 0045-6535
    Electronic ISSN: 1879-1298
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by Elsevier
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  • 4
    Publication Date: 2020-12-17
    Description: Background: It is difficult to assess workers’ exposure to ultrafine particles (UFP) due to the lack of personal sampling equipment available for this particle fraction. The logbook method has been proposed as a general method for exposure assessment. This method measures the time and concentration components of the time-weighted average concentration separately and could be suitable for investigation of UFP exposure. Objectives: In this study, we have assessed workers’ exposure to UFP in a ferrosilicon plant. The main tasks of the furnace workers were identified, and the logbook method was used in combination with stationary measurements of UFP taken as close to the identified task areas as possible. In order to verify the results, respirable particles were collected using stationary sampling in close proximity to the UFP measuring instrument, and personal full-shift sampling of respirable particles was performed simultaneously. Thus, exposure to respirable particles determined using the logbook method could be compared to the results of standard measurement. Methods: The particle number concentration of ultrafine particles was determined using a NanoScan SMPS. Respirable particle concentration and exposure were determined using a sampling train consisting of a pump, filter, filter cassettes, and SKC Cyclone for the respirable fraction. Attendance times for workers at each work location were registered via thorough observations made by the research team. Results: The logbook method for exposure estimation based on stationary sampling equipment made it possible to calculate UFP exposure for workers operating the furnaces at a ferrosilicon plant. The mid-size furnace and the large furnace were evaluated separately. The workers operating the largest furnace were exposed to 1.47 × 104 particles/cm3, while workers operating the mid-size furnace were exposed to 2.06 × 104 particles/cm3, with a mean of 1.74 × 104 particles/cm3. Substantial contributions from the casting area, ladle transport corridor, and both tapping areas were made. Exposure to respirable particles was 2.04 mg/m3 (logbook); 2.26 mg/m3 (personal sampling) for workers operating the large-sized furnace, 3.24 mg/m3 (logbook); 2.44 mg/m3 (personal sampling) for workers operating the medium-sized furnace, and 2.57 mg/m3 (logbook); 2.53 mg/m3(personal sampling) on average of all tappers. The average ratio of these two methods’ results was 1.02, which indicates that the logbook method could be used as a substitute for personal sampling when it is not possible to perform personal sampling, at least within this industry. Conclusions: The logbook method is a useful supplement for exposure assessment of UFP, able to identify the most polluted areas of the workplace and the contribution of different work tasks to the total exposure of workers, enabling companies to take action to reduce exposure.
    Electronic ISSN: 2079-4991
    Topics: Physics
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  • 5
    Publication Date: 2021-07-01
    Print ISSN: 0048-9697
    Electronic ISSN: 1879-1026
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by Elsevier
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