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  • 1
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Air compressibility is important in attaining an accurate quantification of the permeability parameters for refractory castables. Nevertheless, this effect is often neglected in the permeability equations that are found in ceramics literature. The consequences of omitting the compressibility effect in two of the main permeability equations are highlighted and discussed. The permeability to air flow of high-Al2O3 ultra-low-cement refractory castables has been quantified by Darcy's law according to U.S. ASTM C577–96 and European PRE-16th permeability methods, which propose distinct approaches for air compressibility. Forchheimer's equation, which establishes a more realistic dependence between fluid pressure and fluid velocity, also has been used to obtain the permeability constants k1 and k2. Results show that equations proposed by the ASTM and the PRE methods may yield very distinct values of Darcian permeability k1 for the same sample. Forchheimer's equation for compressible fluids provides the best fitting with experimental data.
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this work, the water-expulsion porosimetry technique was used to quantify the permeable pores of self-flow ultralow-cement refractory castables that were treated at 600°–1650°C. Results have shown that the method as proposed in previous works was not valid, because water was not removed continuously from pores, relative to increased pressure. Nevertheless, the maximum pore diameter obtained according to ASTM Method E128-89 could be successfully correlated with other castable physical properties (such as the permeability constants from the Forchheimer equation) and the apparent porosity obtained via the Archimedes technique. Although the apparent porosity decreased as the thermal treatment temperature increased, the pore morphology changed continuously, with the generation of less-tortuous and more-permeable paths for fluid flow.
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Correct estimation of the pressure drop in filtration processes that involve fluid velocity variations is of major importance, because it allows the filtration rate and/or the energy consumed on fluid flow to be more accurately controlled. Permeability of porous filters has been often described by Forchheimer's equation, which establishes a nonlinear dependence between pressure drop and fluid velocity. Two constants, k1 and k2, dependent only on the medium, quantify the viscous and inertial effects on the pressure drop curve. In this work, experimental data of airflow through 10 pores per linear inch ceramic foam filters are used to show that a single sample may have completely distinct permeability constants depending on the data range chosen for analysis. The Darcian permeability constant k1 displays higher variation than the non-Darcian permeability constant k2. The conclusion is that special attention must be taken to represent permeability of highly porous structures in a large velocity range. The predictability of Forchheimer's equation generally worsens when less data are included in the curve fitting, particularly at low velocities. Careful consideration should be made if constants k1 and k2 are intended to be used for permeability estimation beyond the fitting range.
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  • 4
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This work investigated the changes in the permeability of high-alumina self-flowing refractory castables based on calcium aluminate cement (CAC) and hydratable alumina binder (HAB) pretreated between 110° and 1650°C. Permeability constants k1 and k2 were fitted from Forchheimer's equation based on airflow tests conducted at room temperature. The results indicated that dehydration was the main contributing factor for increased permeability in bodies pretreated up to 600°C and that sintering effects prevailed between 900° and 1650°C. Castables based on HAB were less permeable than those based on CAC, a behavior ascribed to the type of hydrates formed and to the particle-packing features of the matrix and the matrix–aggregate interfaces.
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  • 5
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This work describes the use of a new permeametry technique to evaluate microstructural changes that take place in castables with high alumina-fiber content during the dewatering process. It is shown that the mass loss due to cement dehydration and the permeability increase caused by fiber burnout can be independently assessed, based on the fluid dynamic conditions established for the experiment. Control of the pressure drop through the sample was the key procedure used to analyze the phenomenon of interest.
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  • 6
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This article reports on an experimental investigation of the dewatering process of cement-free high-alumina refractory castables. Simultaneous fluid dynamic, thermal, and mass loss effects were investigated during the removal of physically absorbed water at temperatures of 25° to 700°C. The release of steam was decisively affected by the castable's permeability level and the heating rate applied. The analysis of fluid dynamics revealed that at 1°C/min, the main bulk of physical water was released as steam under saturated conditions at 100°C. However, at 5°C/min, steam was trapped within the pores, and water loss was chaotically released and shifted to higher temperatures. Thermal analysis showed that the endothermic boiling of water may result in a critical thermal shock in the castable's structure. Both steam entrapment and thermal shock were more severe with the reduction in the castable's permeability level.
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  • 7
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Considerable efforts have been made to understand the dewatering behavior of refractory castables. Modeling of this process must be based on realistic heat and mass transfer data; hence, consistent values of castable properties are required, particularly permeability values, since these are the most important parameters that govern the process. Permeability values, however, are usually obtained at room temperature and therefore may not reflect the remarkable microstructural changes that take place during water removal. The problem has become more critical for castable compositions based on calcium-free binders, in which the dehydration process is still unclear and explosive spalling is more likely to occur. This study has investigated the behavior of the dynamic permeability of high-alumina calcium-free refractory castables subjected to a drying process up to 700°C. Samples were previously treated at temperatures ranging from 110° to 1650°C to provide information on the castables’ reversible and irreversible microstructural changes. The results revealed fluctuations and a dramatic decrease in the permeability level near 200°C, which may help to explain the occurrence of explosive spalling in this class of castables.
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  • 8
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The literature reports that permeability constants differ in experiments conducted with gases or liquids. This behavior, known as the Klinkenberg effect, has been explained based on the gas-slippage theory. We show here that inertial effects not considered by Darcy's law are the cause of variations in the gas permeability constant, kgas, with the mean pressure, Pm. The dependence of kgas and Pm on fluid flow is fully explained by the proposed model, based on Forchheimer's equation. The use of the gas-slippage theory is unnecessary to explain variations in kgas obtained by Darcy's law.
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  • 9
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 86 (2003), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The purpose of this work was to investigate the drying kinetics of high-alumina, ultra-low-cement refractory castables under continuous heating conditions. Three main drying stages were identified during the castable heat-up and were related to the phase change of free water and to the decomposition of hydrated products present in the body. A clear correlation was found between the actual heating profile inside the castable and the dewatering stages under various heating schedules. Thermal analysis was used to assess the drying temperature that represents the highest risk of steam pressure buildup and, thus, of explosive spalling.
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  • 10
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 83 (2000), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The experimental evaluation of permeability parameters encounters different difficulties, depending on the features of the materials. Traditional steady-state techniques for refractory castables and other highly dense ceramics demand arduous work and require reliable measurements at high pressure and for extremely low flow rates. In this paper, a recent and promising technique known as vacuum-decay permeametry is modified to consider the effect of gas compressibility and fluid inertia. Darcy's law is replaced by Forchheimer's equation, which has been proved to better represent the interactions between fluid and a castable porous medium. The modified method is modeled and applied experimentally to refractory samples with different permeability levels. Results that have been compared to a well-established steady-state permeametry method confirm the validity of the model.
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