ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis and Conformational Analysis of Some 5′-Homoadenosine DerivativesThe syntheses of the homoaadenosines 9-(5-deoxy-β-D-ribo-hexofuranosyl)adenine (2) and 9-(5,6-dideoxy-β-ribo-heptofuranosyl)adenine (3) as well as the 5′-homo-AMP analogue 9-(5,6-dideoxy-6-dideoxy-6-phosphono-β -D-ribo-hexofuranosyl)adenine (4) are described. The conformational parameters of the compounds 2-4 were determined from the observed coupling constants by the method outlined by Altona and Sundaralingam.
Notes:
Die Synthesen der Homoadenosinderivate 9-(5-Desoxy-β-D-ribo-hexofuranosyl)adenin (2) und 9-(5,6-Didesoxy-β-D-ribo-heptofuranosyl)adenin (3) sowie der 5′-Homo-AMP-Analogons 9-(5,6-Didesoxy-6-phosphono-β-D-ribo-hexofuranosyl)adenin (4) werden beschrieben. Die Bestimmung der Pseudorotationsparameter der Verbindungen 2-4 und ihrer Vorstufen erfolgte aus den Kopplungskonstanten nach der Methode von Altona und Sundaralingam.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198419840111
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