ISSN:
1572-8854
Keywords:
C-methylphloracetophenone
;
C-benzylation
;
X-ray crystallography
;
1H-NMR spectroscopy
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract Benzylation of 3-methylphloracetophenone [1-(2,4,6-trihydroxy-3-methylphenyl)ethanone] (3) with benzyl chloride gave 4-acetyl-2,6-dibenzyl-1,5-dihydroxy-2-methylcyclohexa-4,6-dien-3-one (5). Compound 5 crystallizes in the orthorhombic space group Fdd2 with a = 17.586(2), b = 42.891(5), c = 10.279(2) Å, V = 7753(2) Å,3 and Z = 16. When crystals of 5 were dissolved in [D6]acetone the compound underwent tautomerization and a mixture of 5 and its keto form 4 was obtained (keto form/enol form ratio 1:4).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009523804263
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