ISSN:
0170-2041
Keywords:
Asymmetric epoxidation
;
2,4-Dodecadien-7-one, 4,6,10-trimethyl-
;
Maritime pine scale
;
Matsucoccus feytaudi
;
Pheromones
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(2E,4E,6R,10S)-4,6,10-Trimethyl-2,4-dodecadien-7-one (1) - the major component of the sex pheromone of the maritime pine scale - and its three stereoisomers were synthesized by starting from (R)- or (S)-citronellol (4) and employing the asymmetric epoxidation (9 → 10) and the palladium-catalyzed reductive cleavage of the epoxy ring (13 → 14) as the key steps.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199319930165
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