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  • 1
    Publication Date: 1988-03-01
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 2
    Publication Date: 1985-09-15
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 3
    Publication Date: 1989-05-01
    Print ISSN: 0021-8979
    Electronic ISSN: 1089-7550
    Topics: Physics
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  • 4
    Publication Date: 2013-08-31
    Description: In recent years analytical tools to characterize combustor flow have been developed in order to support design. To facilitate anchoring of combustion related physical models and the CFD codes in which they are incorporated, considerable development and application of non-intrusive combustion diagnostic capabilities has occurred. Raman spectroscopy can be used to simultaneously detect all polyatomic molecules present in significant concentrations and to determine gas temperature. This is because all molecules possess a distinct temperature dependent Raman spectrum. A multi-point diagnostic system for non-intrusive temperature and species profiling in rocket engines has been developed at Rocketdyne. In the present effort, the system has been undergoing validation for application to rocket engine component testing. A 4 inch diameter windowed combustor with a coaxial gas-gas injector was chosen for this series of validation experiments. Initially an excimer-pumped tunable dye laser and later a solid state Nd-Yag laser served as excitation sources. The Raman signal was dispersed by a monochromator and detected by a gated, intensified Charged Coupled Device (CCD) array. Experiments were carried out prior to each series of hot fire tests to ensure that the Raman signal detected was due to a spontaneous rather than a stimulated Raman emission process. Over sixty hot fire tests were conducted during the first series of tests with the excimer/dye laser. All hot fire testing was at a mixture ratio of 0.5 and chamber pressures of approximately 100 and approximately 300 psia. The Raman spectra of hydrogen, water vapor and oxygen recorded during single element hot fire tests were reduced and analyzed. A significant achievement was the attainment of single shot Raman spectra in cold flow tests. Unfortunately, the single shot signal-to-noise ratio deteriorated to an unacceptable level during the hot fire testing. Attempts to obtain temperature data from the hydrogen Q1-branch profiles obtained in hot fire tests suggest that potentially complicating factors may render the approach of averaging data on the photodiode array invalid. A second series of hot fire tests was conducted with a 4 element coaxial injector using the Nd-Yag laser. A very compact and portable diagnostics set up was assembled for ease of alignment, relocation and flexibility. Measurements were made at several regions in the chamber in order to map concentration profiles. High spatial resolution and improved signal to noise characteristics were demonstrated.
    Keywords: SPACECRAFT PROPULSION AND POWER
    Type: NASA. Marshall Space Flight Center, Eleventh Workshop for Computational Fluid Dynamic Applications in Rocket Propulsion; p 1619-1634
    Format: application/pdf
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 3061-3071 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work reports the measurements of rate coefficients for excitation transfer reactions of metastable He(2 3S) atoms, produced in 0.3–4 atm of helium, with various reactants presenting a wide range of characteristics. In all cases studied, three-body reaction channels were identified with most probable values of rate coefficients lying in the range from 0.2 to 6.7×10−31 cm6 s−1, for Ne and N2O, respectively. These are generally more than one order of magnitude smaller than previously reported. The interpretation of this discrepancy in terms of a more reactive intermediate He2(Σ*) complex in dynamic equilibrium with the He(2 3S) population seems to be confirmed, and is analyzed in some detail.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 3369-3380 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Measurements and analyses have been made of electron impact ionization and of current growth in pulsed, low-current, prebreakdown discharges in parallel-plane geometry in N2 at very high electric field to gas density ratios E/n and low products of the gas density n and electrode separation d. The E/n range and nd ranges were 1〈E/n〈52 kTd, where 1 Td=10−21 V m2 , and 6×1018 〈nd〈3×1020 m−2 (or 0.02〈pd〈1 Torr cm, where p is pressure) and were below breakdown values. Measurements were made of the transported charge on the time scales of electron transit, ion transit, and metastable decay. Measurements were also made of the growth of steady-state discharge currents as a function of discharge voltage. The contributions of avalanches resulting from ion- and metastable-induced secondary electrons were determined from the ratio of electron-excited N+2 391.4-nm emission integrated over all avalanches to the integrated emission during the laser-initiated electron pulse. Calculations based on ionization by electrons only show good agreement with the measured charge transported during the electron avalanche and with the current multiplication. Analysis of 391.4-nm emission data and of charge transported at E/n≥10 kTd and voltages near breakdown using the assumption of electron impact ionization leads to large apparent secondary electron yields at the cathode which increase significantly with nd. At E/n≥10 kTd, and for the voltages of our experiments, fast N2 produced in charge transfer collisions of N+2 with N2 appears to provide most of the secondary electrons. The apparently small contribution of ionization of N2 by N2, N+2 , N, and N+ is consistent with our assumption that each of these ionization cross sections is equal to that for N2-N2 collisions and so are much smaller than for Ar+ -Ar or Ar-Ar collisions.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 83 (1985), S. 2836-2839 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: This work focuses upon previously encountered problems that have impeded the understanding of the role of He2(3Σu) metastable molecules in the afterglows of electrical discharges into atmospheric pressures of helium containing admixtures of reactants. New data are reported that generally confirm the literature values for the reactivities of this species at high pressures and continue the disagreement with earlier measurements in low pressure plasmas. Results are presented for reactions with HCl and HBr for the first time. A study of systematic dependencies of rates upon molecular parameters is reported which shows that the ratio for bimolecular reactions of vibrationally excited and unexcited He2(3Σu) molecules is largely independent of the identity of the reacting partner. This provides a means for using data on the pressure dependent part of the effective rate of reaction of He(2 3S) atoms to estimate the rate coefficients for the bimolecular reactions of the more elusive He2(3Σu) molecule.
    Type of Medium: Electronic Resource
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