ISSN:
0009-2940
Keywords:
Lithium 5-Methyl-1,3-dithia-5-azacyclohex-2-ylborate - 5-borane
;
5-Methyl-1,3-dithia-5-azacyclohex-2-yllithium
;
Nitrogen heterocycles
;
Sulfur heterocycles
;
Lithium
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Syntheses of the dimers of axial 5-methyl-2-dithiazinyllithium (4) and equatorial 5-methyl-2-diethiazinyllithium-5-borane (5), and lithium 5-methyl-2-dithiazinanylborate-5-borane (6) are reported. Compounds 4, 5, and 6 are configurationally and conformationally stable. The 1H-, 13H-, 13C-, 11B-, and 7Li-NMR study of th reactions of 4 and 5 with BH3—S(CH3)2, BH3 - THF, and CH3I is presented.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300622
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