ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On the Pentachlorothallates(III) K2TlCl5 · 2 H2O and M2TlCl5 · H2O (M = Rb, NH4)The pentachlorothallates(III) K2TlCl5 · 2 H2O and M2TlCl5 · H2O (M = Rb, NH4) were obtained by crystallization from aqueous solutions of TlCl3 and MCl. The crystal structure of the monoclinic K2TlCl5 · 2 H2O contains dimeric Tl2Cl10 anions formed by two edge sharing octahedra. The orthorhombic monohydrates are isotypic with Cs2[TlCl5(OH2)].
Notes:
Die Pentachlorothallate(III) K2TlCl5 · 2 H2O und M2TlCl5 · H2O (M = Rb, NH4) wurden durch Kristallisation aus wäßrigen Lösungen von TlCl3 und MCl erhalten. In der Kristallstruktur des monoklinen K2TlCl5 · 2 H2O sind dimere Anionen in Form von kantenverknüpften Tl2Cl10-Doppeloktaeder enthalten. Die rhombischen Monohydrate sind isotyp mit Cs2[TlCl5(OH2)].
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19834980314
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