ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The structure of the title compound, C14H19N2+·C9H3Cl6O4−·H2O, consists of singly ionized 1,4,5,6,7,7-hexachlorobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid anions and protonated 1,8-bis(dimethylamino)naphthalene cations. In the (8-dimethylamino-1-napthyl)dimethylammonium cation, a strong disordered intramolecular hydrogen bond is formed with N...N = 2.589 (3) Å. The geometry and occupancy obtained in the final restrained refinement suggest that the disordered hydrogen bond may be asymmetric. Water molecules link the anion dimers into infinite chains via hydrogen bonding.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100000664
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