ISSN:
1057-9257
Keywords:
fullerene
;
fullerides
;
charge transfer complexes
;
spectroscopy
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Electrical Engineering, Measurement and Control Technology
,
Physics
Notes:
Some possible uses of vibrational and electronic spectroscopies in characterising the basic interactions in C60 and C70 complexes are pointed out. We report on the wealth of infrared spectra of (usually) single crystals of C60 and C70 clathrates and complexes with organic donors. The changes in the spectral parameters of the complexes in comparison with those of the neutral fullerene molecules are attributed to redistribution of the charge on the spherical C60 or elongated C70 molecules in their compounds. Some general considerations on the origin of the IR, NIR, VIS and UV spectral variations are also given. © 1998 John Wiley & Sons, Ltd.
Additional Material:
14 Ill.
Type of Medium:
Electronic Resource
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