ISSN:
1572-879X
Keywords:
Titanium alkyl catalyst
;
homogeneous trimerization
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reaction of bis(ethyl-3-oxo-butanolato-O1, O3)-bis(2-propanolato)titanium (Tyzor DCR) and 2-isocyanatoethyl methacrylate (IEM) in different molar ratios, at room temperature produced the trimer of IEM in high yields with ethyl acetoacetate, isopropyl acetoacetate, and titanium dioxide, which are derived from Tyzor DCR, as by-products. The reaction products were identified by FTIR,1H NMR,13C NMR, G.C. and M.S. procedures. The study showed that Tyzor DCR acts as a catalyst in this reaction.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00771270
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