ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Tandem chemical laser techniques have been used to detect HF formed through photoelimination from 1,1,1,5,5,5-hexafluoroacetylacetone, HFAA. Information about the HF vibrational population ratios is deduced: N2/N1 〈 0.37 and N1/N0 〈 0.45. This work supports the deduction by Bassett and Whittle that photodecomposition of the enol form of HFAA results mainly in HF elimination and ring closure to a dihydrofuranone, a new type of reaction.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550080607
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