ISSN:
1434-1948
Keywords:
Germacyclopentene
;
Germaimine
;
Photoelectron spectroscopy
;
Ab initio calculations
;
Germanium
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
An unhindered germaimine has been generated and characterized by the coupling of flash vacuum pyrolysis of two different precursors with UV-photoelectron spectroscopy. The Ge=N unit exhibits two ionizations in the low-energy region, corresponding to the ejection of an electron from the nitrogen atom lone pair and from the πGe=N orbital, respectively.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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