ALBERT

Description: The denitrification rate in C2H2-amended intact soil cores and soil N2O fluxes in closed static chambers were monitored in a Mediterranean irrigated maize-cropped field. The measurements were carried out during: (i) a standard fertilization management (SFM) activity and (ii) a manipulation experimental (ME) test on the effects of increased and reduced application rates of urea at the late fertilization. In the course of the SFM, the irrigations following early and late nitrogen fertilization led to pulses of denitrification rates (up to 1300 μg N2O-N m−2 h−1) and N2O fluxes (up to 320 μg N2O-N m−2 h−1), thanks to the combined action of high soil temperatures and not limiting nitrates and water filled pore space (WFPS). During the ME, high soil nitrates were noted in all the treatments in the first one month after the late fertilization, which promoted marked N-losses by microbial denitrification (from 500 to 1800 μg N2O-N m−2 h−1) every time the soil WFPS was not limiting. At similar maize yield responses to fertilizer treatments, this result suggested no competition for N between plant roots and soil microbial community and indicated a probable surplus of nitrogen fertilizer input at the investigated farm. Correlation and regression analyses (CRA) on the whole set of data showed significant relations between both the denitrification rates and the N2O fluxes with three soil physical-chemical parameters: nitrate concentration, WFPS and temperature. Specifically, the response functions of denitrification rate to soil nitrates, WFPS and temperature could be satisfactorily modelled according to simple Michaelis-Menten kinetic, exponential and linear functions, respectively. Furthermore, the CRA demonstrated a significant exponential relationship between N2O fluxes and denitrification and simple empirical functions to predict N2O emissions from the denitrification rate appeared more fitting (higher concordance correlation coefficient) than the predictive empirical algorithm based on soil nitrates, WFPS and temperature. In this regard, the empirically established relationships between the denitrification rate on intact soil cores under field conditions and the soil variables provided local-specific threshold values and coefficients which may effectively work to calibrate and adapt existing N2O process-based simulation models to the local pedo-climatic conditions.

Description: In the structural safety assessment process of existing structures, knowledge of the mechanical properties of the materials is key. Different experimental activities carried out on materials extracted from existing reinforced concrete buildings show a high strength variability, especially concrete. In the past, the lack of standardized quality control for materials and workmanship caused nonuniform and homogeneous properties within the same structure. The most accurate and reliable experimental technique consists of performing direct tests on the materials, but these are considerably expensive and invasive. In this paper, alternative indirect methods that estimate material properties by correlating different physical measures were proved to reduce invasive inspections on existing buildings and infrastructures, especially in built heritage. A complete experimental activity concerning destructive and nondestructive tests was conducted on elements (four portions of a column and a beam portion) removed from an Italian school building built in 1940. Destructive and nondestructive methods were compared and appropriate correlation laws developed to predict the main mechanical properties of the studied material. Reliable correlations were identified considering the pull-out test, Sonic–Rebound (SonReb) combined method and ultrasonic pulse velocities (UPVs). The latter were mapped by tomography, which highlighted the compression properties of concrete in the different structural sections.