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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 26 (2012): GB4018, doi:10.1029/2011GB004192.
    Description: A series of seasonally distributed measurements from the six largest Arctic rivers (the Ob', Yenisey, Lena, Kolyma, Yukon and Mackenzie) was used to examine the magnitude and significance of Arctic riverine DIC flux to larger scale C dynamics within the Arctic system. DIC concentration showed considerable, and synchronous, seasonal variation across these six large Arctic rivers, which have an estimated combined annual DIC flux of 30 Tg C yr−1. By examining the relationship between DIC flux and landscape variables known to regulate riverine DIC, we extrapolate to a DIC flux of 57 ± 9.9 Tg C yr−1for the full pan-arctic basin, and show that DIC export increases with runoff, the extent of carbonate rocks and glacial coverage, but decreases with permafrost extent. This pan-arctic riverine DIC estimate represents 13–15% of the total global DIC flux. The annual flux of selected ions (HCO3−, Na+, Ca2+, Mg2+, Sr2+, and Cl−) from the six largest Arctic rivers confirms that chemical weathering is dominated by inputs from carbonate rocks in the North American watersheds, but points to a more important role for silicate rocks in Siberian watersheds. In the coastal ocean, river water-induced decreases in aragonite saturation (i.e., an ocean acidification effect) appears to be much more pronounced in Siberia than in the North American Arctic, and stronger in the winter and spring than in the late summer. Accounting for seasonal variation in the flux of DIC and other major ions gives a much clearer understanding of the importance of riverine DIC within the broader pan-arctic C cycle.
    Description: Funding for this work was provided through NSF-OPP-0229302 and NSF-OPP-0732985. Additional support to SET was provided by an NSERC Postdoctoral Fellowship.
    Description: 2013-06-14
    Keywords: Arctic ; Dissolved inorganic carbon ; Ocean acidification ; Permafrost ; River biogeochemistry ; Weathering
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2013. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Geochimica et Cosmochimica Acta 124 (2014): 283-308, doi:10.1016/j.gca.2013.09.006.
    Description: The Fraser River basin in southwestern Canada bears unique geologic and climatic features which make it an ideal setting for investigating the origins, transformations and delivery to the coast of dissolved riverine loads under relatively pristine conditions. We present results from sampling campaigns over three years which demonstrate the lithologic and hydrologic controls on fluxes and isotope compositions of major dissolved inorganic runoff constituents (dissolved nutrients, major and trace elements, 87Sr/86Sr, δD). A time series record near the Fraser mouth allows us to generate new estimates of discharge-weighted concentrations and fluxes, and an overall chemical weathering rate of 32 t km-2 y-1. The seasonal variations in dissolved inorganic species are driven by changes in hydrology, which vary in timing across the basin. The time series record of dissolved 87Sr/86Sr is of particular interest, as a consistent shift between higher (“more radiogenic”) values during spring and summer and less radiogenic values in fall and winter demonstrates the seasonal variability in source contributions throughout the basin. This seasonal shift is also quite large (0.709 – 0.714), with a discharge-weighted annual average of 0.7120 (2 s.d. = 0.0003). We present a mixing model which predicts the seasonal evolution of dissolved 87Sr/86Sr based on tributary compositions and water discharge. This model highlights the importance of chemical weathering fluxes from the old sedimentary bedrock of headwater drainage regions, despite their relatively small contribution to the total water flux.
    Description: This work was supported by the WHOI Academic Programs Office and MIT PAOC Houghton Fund to BMV, a WHOI Arctic Research Initiative grant to ZAW, NSF-ETBC grant OCE-0851015 to BPE and TIE, and NSF grant EAR-1226818 to BPE.
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 3
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 125(1), (2020): e2019JG005414, doi:10.1029/2019JG005414.
    Description: A survey of 25 coastal‐draining rivers across the Canadian Arctic Archipelago (CAA) shows that these systems are distinct from the largest Arctic rivers that drain watersheds extending far south of the Arctic circle. Observations collected from 2014 to 2016 illustrate the influences of seasonal hydrology, bedrock geology, and landscape physiography on each river's inorganic geochemical characteristics. Summertime data show the impact of coincident gradients in lake cover and surficial geology on river geochemical signatures. In the north and central CAA, drainage basins are generally smaller, underlain by sedimentary bedrock, and their hydrology is driven by seasonal precipitation pulses that undergo little modification before they enter the coastal ocean. In the southern CAA, a high density of lakes stores water longer within the terrestrial system, permitting more modification of water isotope and geochemical characteristics. Annual time‐series observations from two CAA rivers reveal that their concentration‐discharge relationships differ compared with those of the largest Arctic rivers, suggesting that future projections of dissolved ion fluxes from CAA rivers to the Arctic Ocean may not be reliably made based on compositions of the largest Arctic rivers alone, and that rivers draining the CAA region will likely follow different trajectories of change under a warming climate. Understanding how these small, coastal‐draining river systems will respond to climate change is essential to fully evaluate the impact of changing freshwater inputs to the Arctic marine system.
    Description: This work was only possible through a network of enthusiastic and devoted collaborators. Partners included Polar Knowledge Canada and the Canadian High Arctic Research Station, the Arctic Research Foundation, the Kugluktuk Angoniatit Association, and the Canadian Arctic GEOTRACES Program. We acknowledge support from the Department of Fisheries and Oceans Canada, the Woods Hole Oceanographic Institution Coastal Ocean Institute, The G. Unger Vetlesen Foundation, Jane and James Orr, and the Woods Hole Research Center. Many thanks go to Austin Maniyogena, Angulalik Pedersen, Adrian Schimnowski, JS Moore, Les Harris, Oksana Schimnowski, as well as Barbara Adjun, Amanda Dumond, and Johnny Nivingalok, and the captains and crew of the research vessels CCGS Amundsen and R/V Martin Bergmann, all of whom supported our research and helped with sample collection. Special thanks also go to Valier Galy, Zhaohui “Aleck” Wang, Marty Davelaar, Michiyo Yamamoto‐Kawai, Hugh McLean, Mike Dempsey, Baba Pedersen, Maureen Soon, Katherine Hoering, Sean Sylva, Ekaterina Bulygina, and Anya Suslova for their invaluable contributions during field program planning, preparations, and laboratory analyses. Robert Max Holmes is thanked for many fruitful discussions. We also thank several anonymous reviewers for their helpful comments on the paper's content and structure. All of the data presented in this paper can be found at https://doi.org/10.1594/PANGAEA.908497.
    Keywords: Arctic Rivers ; Geochemistry ; Major ion chemistry ; Stable isotopes ; Northern hydrology
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 119 (2014): 687–702, doi:10.1002/2013JG002442.
    Description: Dissolved organic carbon (DOC) and inorganic carbon (DIC, pCO2), lignin biomarkers, and theoptical properties of dissolved organic matter (DOM) were measured in a gradient of streams and rivers within the Congo Basin, with the aim of examining how vegetation cover and hydrology influences the composition and concentration of fluvial carbon (C). Three sampling campaigns (February 2010, November 2010, and August 2011) spanning 56 sites are compared by subbasin watershed land cover type (savannah, tropical forest, and swamp) and hydrologic regime (high, intermediate, and low). Land cover properties predominately controlled the amount and quality of DOC, chromophoric DOM (CDOM) and lignin phenol concentrations (∑8) exported in streams and rivers throughout the Congo Basin. Higher DIC concentrations and changing DOM composition (lower molecular weight, less aromatic C) during periods of low hydrologic flow indicated shifting rapid overland supply pathways in wet conditions to deeper groundwater inputs during drier periods. Lower DOC concentrations in forest and swamp subbasins were apparent with increasing catchment area, indicating enhanced DOC loss with extended water residence time. Surface water pCO2 in savannah and tropical forest catchments ranged between 2,600 and 11,922 µatm, with swamp regions exhibiting extremely high pCO2 (10,598–15,802 µatm), highlighting their potential as significant pathways for water-air efflux. Our data suggest that the quantity and quality of DOM exported to streams and rivers are largely driven by terrestrial ecosystem structure and that anthropogenic land use or climate change may impact fluvial C composition and reactivity, with ramifications for regional C budgets and future climate scenarios.
    Description: This work was supported by the National Science Foundation as part of the ETBC Collaborative Research: Controls on the Flux, Age, and Composition of Terrestrial Organic Carbon Exported by Rivers to the Ocean (0851101 and 0851015).
    Description: 2014-10-30
    Keywords: Dissolved organic matter ; Lignin ; CDOM ; pCO2 ; Aquatic ; Hydrology
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
    Publication Date: 2017-08-21
    Description: Human appropriation of land for agriculture has greatly altered the terrestrial carbon balance, creating a large but uncertain carbon debt in soils. Estimating the size and spatial distribution of soil organic carbon (SOC) loss due to land use and land cover change has been difficult but is a critical step in understanding whether SOC sequestration can be an effective climate mitigation strategy. In this study, a machine learning-based model was fitted using a global compilation of SOC data and the History Database of the Global Environment (HYDE) land use data in combination with climatic, landform and lithology covariates. Model results compared favorably with a global compilation of paired plot studies. Projection of this model onto a world without agriculture indicated a global carbon debt due to agriculture of 133 Pg C for the top 2 m of soil, with the rate of loss increasing dramatically in the past 200 years. The HYDE classes “grazing” and “cropland” contributed nearly equally to the loss of SOC. There were higher percent SOC losses on cropland but since more than twice as much land is grazed, slightly higher total losses were found from grazing land. Important spatial patterns of SOC loss were found: Hotspots of SOC loss coincided with some major cropping regions as well as semiarid grazing regions, while other major agricultural zones showed small losses and even net gains in SOC. This analysis has demonstrated that there are identifiable regions which can be targeted for SOC restoration efforts.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 6
    Publication Date: 2008-11-01
    Print ISSN: 0034-4257
    Electronic ISSN: 1879-0704
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Published by Elsevier
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  • 7
  • 8
    Publication Date: 2017-05-05
    Description: We discuss concentrations of dissolved CH4, N2O, O2, NO3− and NH4+, and emission fluxes of CH4 and N2O for river sites in the western Congo Basin, Republic of Congo (ROC). Savannah, swamp forest and tropical forest samples were collected from the Congo main stem and seven of its tributaries during November 2010 (41 samples; wet season) and August 2011 (25 samples; dry season; CH4 and N2O only). Dissolved inorganic nitrogen (DIN: NH4++ NO3−; wet season) was dominated by NO3− (63 ± 19 % of DIN). Total DIN concentrations (1.5–45.3 µmol L−1) were consistent with the near absence of agricultural, domestic and industrial sources for all three land types. Dissolved O2 (wet season) was mostly undersaturated in swamp forest (36 ± 29 %) and tropical forest (77 ± 36 %) rivers but predominantly supersaturated in savannah rivers (100 ± 17 %). The dissolved concentrations of CH4 and N2O were within the range of values reported earlier for sub-Saharan African rivers. Dissolved CH4 was found to be supersaturated (11.2–9553 nmol L−1; 440–354 444 %), whereas N2O ranged from strong undersaturation to supersaturation (3.2–20.6 nmol L−1; 47–205 %). Evidently, rivers of the ROC are persistent local sources of CH4 and can be minor sources or sinks for N2O. During the dry season the mean and range of CH4 and N2O concentrations were quite similar for the three land types. Wet and dry season mean concentrations and ranges were not significant for N2O for any land type or for CH4 in savannah rivers. The latter observation is consistent with seasonal buffering of river discharge by an underlying sandstone aquifer. Significantly higher wet season CH4 concentrations in swamp and forest rivers suggest that CH4 can be derived from floating macrophytes during flooding and/or enhanced methanogenesis in adjacent flooded soils. Swamp rivers also exhibited both low (47 %) and high (205 %) N2O saturation but wet season values were overall significantly lower than in either tropical forest or savannah rivers, which were always supersaturated (103–266 %) and for which the overall means and ranges of N2O were not significantly different. In swamp and forest rivers O2 saturation co-varied inversely with CH4 saturation (log %) and positively with % N2O. A significant positive correlation between N2O and O2 saturation in swamp rivers was coincident with strong N2O and O2 undersaturation, indicating N2O consumption during denitrification in the sediments. In savannah rivers persistent N2O supersaturation and a negative correlation between N2O and O2 suggest N2O production mainly by nitrification. This is consistent with a stronger correlation between N2O and NH4+ than between N2O and NO3−. Our ranges of values for CH4 and N2O emission fluxes (33–48 705 µmol CH4 m−2 d−1; 1–67 µmol N2O m−2 d−1) are within the ranges previously estimated for sub-Saharan African rivers but they include uncertainties deriving from our use of basin-wide values for CH4 and N2O gas transfer velocities. Even so, because we did not account for any contribution from ebullition, which is quite likely for CH4 (at least 20 %), we consider our emission fluxes for CH4 to be conservative.
    Print ISSN: 1726-4170
    Electronic ISSN: 1726-4189
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 9
    Publication Date: 2006-04-01
    Print ISSN: 0034-4257
    Electronic ISSN: 1879-0704
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Published by Elsevier
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  • 10
    Publication Date: 2016-11-11
    Description: We report concentrations of dissolved CH4, N2O, O2, NO3− and NH4+, and corresponding CH4 and N2O emissions for river sites in savanna, swamp forest and tropical forest, along the Congo main stem and in several of its tributary systems of the Western Congo Basin, Republic of Congo, during November 2010 (41 samples; ''wet season'') and August 2011 (25 samples; ''dry season''; CH4 and N2O only). Dissolved inorganic nitrogen (DIN: wet season; NH4+ +  NO3−) was dominated by NO3− (63 ± 19 % of DIN), total DIN concentrations (1.5–45.3 nmol L−1) being consistent with small agricultural, domestic and industrial sources. Dissolved O2 (wet season) was mostly under-saturated in swamp forest (36 ± 29 %) and tropical forest (77 ± 36 %) rivers but predominantly super-saturated in savannah rivers (100 ± 17 %). Dissolved CH4 and N2O were within previously reported ranges for sub-Saharan African rivers. While CH4 was always super-saturated (11.2–9553 nmol L−1; 440–354 400 %), N2O ranged from strong under-saturation to strong super-saturation (3.2–20.6 nmol L−1; 47–205 %). Evidently, rivers of the ROC are persistent local sources of tropospheric CH4 but can be small sources or sinks for N2O. Dry season concentration means and ranges of CH4 and N2O were indistinguishable for all three land types and seasonal differences in means and ranges were not significant for N2O for any land type or for CH4 in savannah rivers; the latter is consistent with seasonal buffering of river discharge by an underlying sandy-sandstone aquifer. By contrast, swamp and forest river CH4 was significantly higher in the wet season, possibly reflecting CH4 derived from floating macrophytes during flooding and/or enhanced methanogenesis in adjacent flooded soils. Swamp rivers exhibited both low (47 %) and high (205 %) N2O saturations but wet season values were overall significantly lower than in either tropical forest or savannah rivers, which were always super-saturated (103–266 %) and for which the overall means and ranges of N2O were not significantly different. In swamp and forest rivers % O2 co-varied negatively with log % CH4 and positively with % N2O. The strong positive N2O–O2 correlation in swamp rivers was coincident with strong N2O and O2 under-saturation, indicating N2O consumption by sediment denitrification. In savannah rivers persistent N2O super-saturation and a negative N2O–O2 correlation may indicate N2O production mainly by nitrification, consistent with a stronger correlation between N2O and NH4+ than between N2O and NO3−. Our range in CH4 and N2O emissions fluxes (33–48 705  μmol CH4 m−2 d−1; 1–67 μmol N2O m−2 d−1), is wider than previously estimated for sub-Saharan African rivers but it includes uncertainties deriving from our use of ''basin-wide'' values for CH4 and N2O gas transfer velocities. Even so, because we did not account for any contribution from ebullition, which for CH4 is likely to be at least 20 %, our emissions estimates for CH4 are probably conservative.
    Print ISSN: 1810-6277
    Electronic ISSN: 1810-6285
    Topics: Biology , Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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