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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 41 (1990), S. 743-748 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Heißgaskorrosion von alpha-Siliciumcarbid und beta-SiliciumnitridDer Einfluß der Heißgaskorrosion auf die Bruchfestigkeit von reaktionsgesintertem alpha-Siliciumcarbid und beta-Siliciumnitrid bei Raumtemperatur wird untersucht. Dazu werden die Werkstoffe im Sprühversuch und im Tauchversuch bei 900 bis 1100°C untersucht. Die Ergebnisse zeigen, daß nach Einwirkung von Natriumsulfat und Natriumsulfat/Natriumchlorid-Gemischen die Bruchfestigkeit deutlich verringert ist. Die statische Auswertung der Ergebnisse - mittels kumulativer Wahrscheinlichkeit und Weibull-Statistik - ermöglicht eine bessere Darstellung in Balkendiagrammen und bei „student t“-Versuchen.Die fraktographische Untersuchung von Siliciumnitrid nach Einwirkung von Natriumsulfat zeigt, daß die Binderphase zwischen den linsenförmigen Körnern bevorzugt angegriffen ist. Der Mechanismus des Angriffs durch Salzschmelzen und die Methoden zur Verarbeitung der Daten im Hinblick auf die Ermittlung der möglichen Belastbarkeit werden erörtert. Es wird vorgeschlagen, diese Keramik als Ersatz für Metalle im gegenwärtig üblichen Bereich der Temperaturen und der angreifenden Medien zu verwenden, wo sie hinsichtlich Korrosionsbeständigkeit den Metallen überlegen sind; diese Anwendung sollte gegenüber einer Erhöhung der Betriebstemperatur bevorzugt werden.
    Notes: The effect of hot salt corrosion on the room temperature fracture strength of reaction sintered α silicon carbide and β silicon nitride is investigated. Exposure is carried out using both spray and immersion tests in the temperature range 900-1100°C. The results show a significant reduction in fracture strength following exposure to sodium sulphate and sodium sulphate/chloride environments. Statistical analysis of the results using both cumulative probability and Weibull statistics gives improved data presentation to bar charts and student t tests.Fractographic examination of silicon nitride samples after exposure to sodium sulphate show the preferential attack of the binder phase between the lenticular grains. The mechanism of molten salt attack and methods of data presentation for safe load prediction are discussed. It is suggested that these ceramics be used to replace metals at current operating temperatures in contaminant conditions where they show superior corrosion resistance rather than to use them to increase operating temperatures.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 8 (1962), S. 335-339 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid-liquid dispersions containing various volume fractions of a petroleum solvent dispersed in water have been studied in laminar and turbulent flow conditions. If one assumes that the dispersion behaves as a single-phase fluid, measured friction factors may be used to calculate an effective viscosity of the mixture.In laminar flow, viscosities were found to be a function of capillary diameter, possibly due of the formation of a thin film of continous phase adjacent to the capillary wall. The thickness of this film was determined to be of the order of 10 to 25 μ, which is probably of the order of the average size of the droplets.Up to 20% solvent, the relative fluidity (or viscosity) of the dispersions was the same in laminar, vertical turbulent, and horizontal turbulent flow. In the laminar flow case viscosity decreased somewhat with flow rate and became essentially constant at a Reynolds number of about 1,000.In vertical turbulent flow all dispersions behaved as Newtonian fluids, and a single curve (Figure 6) is presented to predict fluidities. The 35 and 50% dispersions in horizontal flow exhibited non-Newtonian characteristics and had effective fluidities considerably less than the same dispersion in vertical flow but agreed with the horizontal turbulent flow results of Baron, et al. The apparent non-Newtonian behavior could be due to phase separation in the horizontal tube.Corrected laminar flow fluidities for dispersions with 35 and 50% solvent deviated from the vertical turbulent flow results. Reasons for this are unexplained. In laminar flow also, tube orientation affected the viscosity of the 50% dispersion.
    Additional Material: 7 Ill.
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  • 3
    Publication Date: 1962-06-01
    Print ISSN: 0001-1541
    Electronic ISSN: 1547-5905
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Published by Wiley on behalf of American Institute of Chemical Engineers.
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