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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Materials and structures 20 (1987), S. 323-333 
    ISSN: 1359-5997
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Architektur, Bauingenieurwesen, Vermessung
    Beschreibung / Inhaltsverzeichnis: Summary The shrinkage of concrete is generally determined using the standards. When shrinkage is measured over a long period of time, deformation is found to be larger than predicted by the standards. Therefore it seems to be interesting to measure shrinkage on different samples for a relatively long period of time. In this paper, we do not suggest a new model, but present the experimental measurements that can be used to check or develop any model. Our samples are divided into five series according to the examined parameters: (I) cylinders with different diameters; (II) prism with different dimensions; (III) different quality of cement paste; (IV) concrete with same workability but different cement content; (V) variability. The following empirical Equation 1 was used to link shrinkage and time of drying: ɛ=a (t/b+t) n . The coefficientsa, b andn were fitted using the least-square method. This allows us to see the influence of some factors on shrinkage. All samples were cast using the same aggregates and the same cement type (CPN). In some cases we also used a superplasticizer. Both axial and superficial shrinkage have been measured. As the data seem to fit correctly Equation 1 the following conclusions can be drawn: the final shrinkage,a, is decreasing linearly with increasing diameter. The slope depends on the concrete mixture. It is obvious that for a large diameter final shrinkage will reach an asymptotic line; the timet 1/2 needed to obtain half of the final shrinkage is increasing with the diameter ϕ and, as a first approximation, we gett 1/2=Aϕ+Bϕ2; therefore the theory of diffusion does not apply for small diameters; the coefficientn increases also with the diameter, it reaches asymptotically the value of 1. It varies between 0.45 and 0.8 as seen by our measurements, and the functionn=1−C e−dϕ fits correctly. If we assume that Equation 1 describes realistically the behaviour of concrete during drying, the coefficientsa andn should not vary with the sample dimension. We should not forget that shrinkage is a complex phenomenon and therefore cannot be described by such a simple equation. From our measurement we can draw the following conclusions: (i) there is no significant difference between the shrinkage of samples cast or sawed; (ii) when the volume of cement paste is constant, shrinkage is almost uninfluenced by the W/C ratio; (iii) the superplasticizer increases shrinkage slightly, but this increase is compensated by the decrease in W/C ratio; (iv) the cement content does not influence the shrinkage, if the workability is constant; (v) variability can be drastically reduced when precautions are taken to measure deformation during the first minutes of drying.
    Notizen: Résumé Pour évaluer les déformations dues au retrait, on utilise couramment les valeurs indiquées par les normes existantes; toutefois, lorsque l'on effectue des mesures pendant une longue période, on constate que les déformations sont plus importantes que celles préconisées. Dans cet article, nous présentons des résultats expérimentaux pouvant être utilisés pour contrôler la validité des modèles existants ou pour en développer de nouveaux, car nous avons pris en considération plusieurs paramètres. Pour décrire le retrait en fonction du temps des dessiccation, nous avons admis la fonction ɛ=a(t/b+t) n . Les coefficientsa, b etn ont été déterminés par la méthode des moindres carrés. Des mesures effectuées on peut tirer les conclusions suivantes: (i) le retrait final diminue lorsque le diamètre des échantillons augmente; (ii) le temps nécessaire pour atteindre la moitié du retrait final est, en première approximation, de la formet 1/2=A ϕ+B ϕ 2; (iii) l'exposantn augmente avec le diamètre et tend vers 1; la fonctionn=1−C e−dϕ semble convenir; (iv) la différence entre le retrait des éprouvettes sciées ou moulées est négligeable; (v) pour un même volume de pâte de ciment, le retrait est peu influencé par le rapport E/C; (vi) le superfluidifiant utilisé augmente faiblement le retrait mais cette augmentation est compensée par la diminution que l'on peut opérer sur le rapport E/C; (vii) le dosage en ciment n'influence pas le retrait lorsque l'ouvrabilité du béton est maintenue constante; (viii) la variabilité du retrait diminue fortement si des précautions sont prises pour mesurer les déformations pendant les premières minutes de dessiccation.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of materials science 33 (1998), S. 1745-1752 
    ISSN: 1573-4803
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract The workability and mechanical properties of mortar containing shredded automobile and truck tyres were evaluated. Two different shapes of rubber particles were used as constituents of mortar: (1) granules about 2 mm in diameter, and (2) shreds having two sizes which were, nominally, 5.5 mm×1.2 mm and 10.8 mm×1.8 mm (length×diameter). As expected, the geometry of the rubber particles influenced the fracture behaviour of rubber-containing mortar. The addition of rubber led to a decrease in flexural strength and plastic shrinkage cracking of mortar. The crack width and crack length due to plastic shrinkage were reduced for mortar containing the 10.8×1.8 mm rubber shreds compared with a mortar without shreds. The rheological properties of the mortar containing rubber shreds were comparable to those of a mortar without rubber and yielded lower plastic viscosity than a mortar containing 25.4 mm×15 μm (length×diameter) polypropylene fibres. The alkaline stability of rubber in mortar was also evaluated by immersing rubber shreds in NaOH and Ca(OH)2 solutions for 4 mon and the results showed that there is less than 20% change in stress and strain value. The findings of the research suggest that automobile and truck tyres can be recycled by shredding and incorporating them into mortar and probably concrete for certain infrastructural applications. © 1998 Chapman & Hall
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    ISSN: 1573-4803
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract Water molecular dynamics in a hardened Portland cement were characterized by proton Fourier transform nuclear magnetic resonance (NMR) at 400 MHz. Three different types of water molecule (physically bound, chemically bound and porous trapped) were observed. When the hardened cement sample was heated at 105 °C, the physically bound water diffused out of the sample as a function of the heating time while the chemically bound water remained in a stable form. A trace amount of the porously trapped water was also detected to remain in the cavities of the hardened cement even after heating for up to 20 h at this temperature. The loss of the physically bound water proved to be a diffusion-controlled process as evidenced from the NMR data and from a gravimetric technique. A Pake doublet was observed in the NMR spectra. This is a result of the oscillation of the water molecules with hindered molecular motions due to their entrapment in the cement pores. Soaking the dried samples in water resulted in the diffusion of water back into the hardened cement as physically bound water. Nuclear spin–spin relaxation time, T2-weighted imaging showed that the distribution of the physically bound water inside the cylindrical sample formed a doughnut shape after overnight soaking. The residual air in the cement pores may have slowed down the diffusion rate of the water molecules back into the dried cement. © 1998 Kluwer Academic Publishers
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2006-01-23
    Print ISSN: 0003-6951
    Digitale ISSN: 1077-3118
    Thema: Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Publikationsdatum: 2006-12-04
    Print ISSN: 0003-6951
    Digitale ISSN: 1077-3118
    Thema: Physik
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Publikationsdatum: 2012-10-01
    Beschreibung: A gem-grade apatite from Brazil of general composition (Ca,Na) 10 [(P,Si,S)O 4 ] 6 (F,Cl,OH) 2 has been studied using single-crystal X-ray and neutron diffraction together with synchrotron powder X-ray diffraction. Earlier electron microscopy studies had shown the nominally single-phase apatite contains an abundant fluorapatite (F - Ap) host, together with chloro-hydroxylapatites (Cl/OH - Ap) guest phases that encapsulate hydroxylellestadite (OH - El) nanocrystals. While the latter features appear as small (200–400 nm) chemically distinct regions by transmission electron microscopy, and can be identified as separate phases by synchrotron powder X-ray diffraction, these could not be detected by single-crystal X-ray and neutron analysis. The observations using neutron, X-ray and electron probes are however consistent and complementary. After refinement in the space group P 6 3 / m the tunnel anions F – are fixed at z = 1/4 along 〈001〉, while the anions Cl – and OH – are disordered, with the suggestion that O-H···O-H··· hydrogen-bonded chains form in localized regions, such that no net poling results. The major cations are located in the 4 f A F O 6 metaprism (Ca+Na), 6 h A T O 6 X tunnel site (Ca only), and 6 h B O 4 tetrahedron (P+Si+S). The structural intricacy of this gem stone provides further evidence that apatite microstructures display a nano-phase separation that is generally unrecognized, with the implication that such complexity may impact upon the functionality of technological analogues.
    Print ISSN: 0003-004X
    Digitale ISSN: 1945-3027
    Thema: Geologie und Paläontologie
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Publikationsdatum: 2012-09-14
    Beschreibung: Silver nanocluster silica composite coatings were deposited by radio frequency co-sputtering technique on several substrates. This versatile method allows tailoring of silver content and antibacterial behaviour of coatings deposited on glasses, ceramics, metals and polymers for several applications. Coating morphology and composition as well as nanocluster size were analyzed by means of UV-Visible absorption, X-ray diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), electron dispersive spectroscopy (EDS), X-ray Photoelectron Spectroscopy (XPS) and Atomic Force Microscopy (AFM). The antibacterial effect was verified through the inhibition halo test against standard bacterial strain, Staphylococcus aureus , before and after sterilization process. Tape test demonstrated a good adhesion of the coatings to the substrates.
    Print ISSN: 1757-8981
    Digitale ISSN: 1757-899X
    Thema: Maschinenbau
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Publikationsdatum: 2010-11-01
    Print ISSN: 1293-2558
    Digitale ISSN: 1873-3085
    Thema: Chemie und Pharmazie , Physik
    Publiziert von Elsevier
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Publikationsdatum: 2014-04-03
    Beschreibung: Two new mineral species, trinepheline (NaAlSiO 4 ) and fabriesite (Na 3 Al 3 Si 3 O 12 · 2H 2 O), are described from late-stage metamorphic veins of the jadeite deposit of Tawmaw-Hpakant (Myanmar). Both minerals and their names were approved by the IMA Commission on New Minerals and Mineral Names (IMA 2012–024 and IMA 2012–080). The name trinepheline is known in literature for the polymorphs of synthetic NaAlSiO 4 with a value of the c parameter that is three times that of nepheline. Fabriesite is named in memory of Jacques Fabriès (1932–2000), former professor of the "Muséum National d’Histoire Naturelle" in Paris (France). Fabriesite and trinepheline occur intimately intergrown together with nepheline, more rarely with albite and other feldspar-group phases such as banalsite and stronalsite; other associated minerals are jadeite and secondary products like natrolite and harmotome. All phases have been identified via electron backscatter diffraction (EBSD) patterns. Both fabriesite and trinepheline are pseudomorph after jadeite and occur as skeletal allotriomorphic crystals up to 15–20 μm long and 5–10 μm wide. They are white to yellowish in hand specimen, colourless in thin section; the streak is white and the lustre appears vitreous to greasy; they are non-fluorescent; Mohs’ hardness is 5–51/2. Empirical formulae (EMPA analysis) are very close to the ideal compositions with traces of Ca and K for trinepheline, and of Ca, K, Ba, Mg, Fe, and Mn for fabriesite. Calculated densities are 2.642 g cm –3 for trinepheline (space group P 6 1 , a = 9.995 Å, c = 24.797 Å) and 2.386 g cm –3 for fabriesite (space group Pna 2 1 , a = 16.426 Å, b = 15.014 Å, c = 5.223 Å), respectively. The strongest five lines in the calculated X-ray powder diffraction patterns [ d (Å) ( I )( hkl )] are: 3.163(100)(122), 3.834(81)(023), 4.133(49)(006), 3.272(40)(120) and 2.403(31)(127) for trinepheline; 3.41(100)(240), 4.41(77)(201), 2.97(70)(421), 2.61(40)(002) and 8.21(36)(200) for fabriesite.
    Print ISSN: 0935-1221
    Digitale ISSN: 1617-4011
    Thema: Geologie und Paläontologie
    Publiziert von Schweizerbart
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Publikationsdatum: 2014-05-17
    Beschreibung: Lead-containing (Pb- B - X )-2 H apatites encompass a number of [ A F ] 4 [ A T ] 6 [( B O 4 ) 6 ] X 2 compounds used for waste stabilization, environmental catalysis and ion conduction, but the influence of the stereochemically active lone-pair electrons of Pb 2+ on crystal chemistry and functionality is poorly understood. This article presents a compilation of existing structural data for Pb apatites that demonstrate paired electrons of Pb 2+ at both the A F and A T results in substantial adjustments to the Pb F O 6 metaprism twist angle, . New structure refinements are presented for several natural varieties as a function of temperature by single-crystal X-ray diffraction (XRD) of vanadinite-2 H (ideally Pb 10 (VO 4 ) 6 Cl 2 ), pyromorphite-2 H (Pb 10 (PO 4 ) 6 Cl 2 ), mimetite-2 H / M (Pb 10 (As 5+ O 4 ) 6 Cl 2 ) and finnemanite-2 H (Pb 10 (As 3+ O 3 ) 6 Cl 2 ). A supercell for mimetite is confirmed using synchrotron single-crystal XRD. It is suggested the superstructure is necessary to accommodate displacement of the stereochemically active 6s 2 lone-pair electrons on the Pb 2+ that occupy a volume similar to an O 2– anion. We propose that depending on the temperature and concentration of minor substitutional ions, the mimetite superstructure is a structural adaptation common to all Pb-containing apatites and by extension apatite electrolytes, where oxide ion interstitials are found at similar positions to the lone-pair electrons. It is also shown that plumbous apatite framework flexes substantially through adjustments of the Pb F O 6 metaprism twist-angles () as the temperature changes. Finally, crystal-chemical [100] zoning observed at submicron scales will probably impact on the treatment of diffraction data and may account for certain inconsistencies in reported structures.
    Print ISSN: 0026-461X
    Digitale ISSN: 1471-8022
    Thema: Geologie und Paläontologie
    Standort Signatur Erwartet Verfügbarkeit
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