ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. Trinitromethyl radicals generated electrochemically on the Pt electrode are capable of detaching hydrogen atoms from substrates such as acetonitrile, toluene, benzyl chloride, cyclohexane, and diethyl ether; fragmentation of the TNM radical into inorganic compounds predominates when hydrogen detachment is either impossible or hindered. 2. Detachment of halogen atoms from halogen-containing organic substrates, and addition of the TNM radicals to diene and their recombination with intermediate alkyl radicals, all take place here, but only to a limited degree.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00950969
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