ISSN:
0721-3115
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
The nitrolysis of hexamethylenetetramine (hexamine, HA) and 1,3,5-trioxane was studied by NMR spectrometry. It was found that the structure of the nitrolysis products of the trioxane could be monomethylenedinitrate, dioxymethylenenitronitrate and trioxymethylenenitronitrate, O2N(OCH2)nONO2(n = 1,2,3). Comparison of the 1H and 13C spectra of the nitrolysis mixture of HA with the nitrolysis products of trioxane proved that in the nitrolysis mixture of HA the methylene group which cannot be used to form 1,3,5-triazacyclohexane (hexogen, RDX)appears in compound (2) and not in compound (1).
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prep.19950200208
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