ISSN:
1572-8927
Keywords:
CuSO4
;
aqueous solutions
;
diffusion
;
conductance
;
osmotic coefficients
;
Onsager coefficientsl ij
;
irreversible thermodynamics
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Experimental thermodynamic and transport data are presented for aqueous CuSO4 solution at 25°C from low concentrations to near saturation. Included are diffusion coefficients (Rayleigh interferometry), electrical conductances (DC method), and osmotic coefficients (isopiestic). These data and corresponding literature data are critically compared, as are literature density data. The resulting best values, together with previously compared transference number results, provide an extensive set of critically reviewed data for aqueous CuSO4. Onsager coefficientsl ij have been calculated for this salt and are compared with data for other valence types.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00647737
Permalink