ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The chromium(V) complex [bipyH2][CrOCl5] reacts with MeCN to yield the octahedral chromium(III) complex [CrCl3(bipy)(NCMe)], the nitrile ligand of which can be replaced by other ligands to give [CrCl3(bipy)L] complexes (L = py, pyO, and Ph3PO). However, reactions of [bipyH2]-[CrOCl5] with higher nitriles RCN (R = Et, n-Pr, Ph, or PhCH2) or with MeNO2 all lead to the isolation of [CrCl3(bipy)]n (n most probably being 2), which may also be prepared by thermal decomposition of [CrCl3(bipy)(NCMe)].
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00618232
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