ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Description / Table of Contents:
Several N-acylaminohydroquinones containing vinyl groups were prepared. N-(2,5-dimethoxy-4-methyl)phenyl-p-vinylbenzamide could be polymerized radically. The demethylation of the polymeric hydroquinone dimethyl ether (3) yielded a redox polymer, in which the redox groups (hydroquinone/quinone) are linked by an aminocarbonyl group to the polymer chain. Also a number of N-acylaminohydroquinones was synthesized as model compounds of low molecular weight, and their redox potentials were determined by potentiometric titration.
Notes:
Einige vinylgruppenhaltige N-Acylaminohydrochinone wurden dargestellt. N-(2,5-Dimethoxy-4-methyl)phenyl-p-vinylbenzamid (2) konnte radikalisch polymerisiert werden. Die Entmethylierung des polymeren Hydrochinondimethyläthers (3) führte zum Redoxpolymeren, in dem die Redoxgruppen (Hydrochinon/Chinon) über Aminocarbonyl-Brücken mit der Polymerenkette verknüpft sind. Es wurde ebenfalls eine Anzahl niedermolekularer Modellsubstanzen vom Typ der N-Acylaminohydrochinone dargestellt und deren Redoxpotentiale potentiometrisch bestimmt.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1974.021751108
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