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  • 1
    Call number: Q 2435/37 ; ZSP-319/C-37 ; MOP Per 581(3/37)
    In: Geodätische und Geophysikalische Veröffentlichungen : Reihe 3, Physik der festen Erde, Heft 37
    Type of Medium: Monograph available for loan
    Pages: 191 Seiten , Illustrationen, Karten , 1 Karte
    ISSN: 0435-6187
    Series Statement: Geodätische und Geophysikalische Veröffentlichungen : Reihe 3, Physik der festen Erde 37
    Language: German , English , Russian
    Note: Kartenbeilage unter dem Titel: Berge der Deutsch-Sowjetischen Freundschaft : Antarktika Enderby-Land = Gory Nemecko-Sovetskoj Družby : Antarktika Zemlja Ėnderbi 〈1 : 10 000〉 , Inhaltsverzeichnis Vorwort Rezjume Abstract Teil I: Allgemeiner Teil 1. Arbeitsprogramm und Arbeitsgebiet (S. MEIER) 1.1. Arbeitsprogramm 1.2. Meßmethoden 1.3. Hauptarbeitsgebiet Hays-Gletscher 1.4. Lokale Eiskappe von Molodežnaja 1.5. Vergleichsobjekt Campbell-Gletscher 2. Expeditionsverlauf (K. DRESZLER) 3. Ausrüstung (K. DRESZLER) 4. Klimatische Bedingungen (K. DRESZLER) Teil II: Meßverfahren und -ergebnisse 1. Geodätische und kartographische Grundlagen 1.1. Festpunkte (R. EGER) 1.2. Kartenunterlagen (K. DRESZLER) 2. Geodätisch-glaziologische Traverse 2.1. Erkundung und Signalisierung (S. MEIER} 2.1.1. Verlauf der Traverse 2.1.2. Erkundung, Punktabstand 2.1.3. Signalisierung 2.2. Lagemessung und trigonometrische Höhenübertragung 2.2.1. Streckenmessung 2.2.2. Winkelmessung 2.2.3. Technologischer Ablauf 2.2.4. Auswertung der Messungsergebnisse 2.3. Astronomische Beobachtungen (R. DIETRICH) 2.4. Deformationsraten (S. MEIER) 2.5. Barometrisches Höhenprofil (R. DIETRICH) 2.5.1. Zielstellung 2.5.2. Das Meßverfahren 2.5.3. Diskussion der Fehlereinflüsse 2.5.3.1. Fehler im angenommenen theoretischen Modell 2.5.3.2. Fehler bei der praktischen Messung 2.5.4. Ergebnisse 2.6. Oberflächenneigungen (S. MEIER) 2.7. Photogrammetrische Geländeaufnahmen (K. DRESZLER) 2.7.1. Zunge des Hays-Gletschers 2.7. 2. Einzugsgebiet des Hays-Gletschers 2.8. Glaziologische Arbeiten (S. MEIER) 2.8.1. Ziel der Feldarbeiten 2.8.2. Pegelablesungen 2.8.3. Überblick über Firnaufgrabungen. Firnschichtung 2.8.4. Dichtemessungen 2.8.5. Firntemperaturmessungen 2.8.6. Akkumulationsraten und -profile 2.8.7. Oberflächenbeobachtungen 3. Bewegungsmessungen am Hays- und Campbell-Gletscher 3.1. Photogrammetrjsche Bewegungsmessungen am Hays- und Campbell-Gletscher (K. DRESZLER) 3.2. Auswertung photogrammetrischer Bewegungsmessungen (S. MEIER) 3.2.1. Auswerteziel 3.2.2. Auswertefolge 3.2.3. Besonderheiten 3.2.4. Ergebnisse 3.2.5. Meßfehler 3.3. Trigonometrische Bewegungsmessungen am Campbell-Gletscher (R. EGER) 4. Eisdickenmessungen und Meereslotungen 4.1. Ergebnisse von Radarsondierungen (Messung V. I. CUDAKOV) G. W. TREPOV, Bearbeitung S. MEIER) 4.2. Ergebnisse von Gravimetermessungen (Messung N.D. TRETJAKOV, Bearbeitung C. OELSRER) 4.3. Drahtlotung Spooner-Bucht (S. MEIER) 5. Sonderarbeiten 5.1. Results of meteorological Observations at Camp Abendberg and during the oversnow traverses (E. KAUP) 5.1.1. Meteorological observations at Camp Abendberg 5.1.2. Meteorological Observations during the oversnow traverses 5.2. Küstennahe Ablation und temperierte Firnschicht (S. MEIER) 5.3. Analyse der Sedimentprobe vom Boden der Spooner-Bucht (J. ELIDBERG, F. FALK) 5.4. Refraktionsbeobachtungen (R. EGER) 5.4.1. Beobachtungsprogramm 5.4.2. Beobachtungsergebnisse 5.5. Untersuchungen zur barometrischen Höhenbestimmung von Einzelpunkten (R. DIETRICH) 5.5.1. Einführung 5.5.2. Beobachtungsverfahren und -geräte 5.5.3. Auswertungsmethode 5.5.4. Ergebnisse 5.5.5. Zusammenfassung und Schlußfolgerungen 5.6. Topographische Aufnahme der Berge der Deutsch-Sowjetischen Freundschaft (K. DRESZLER) 5.6.1. Allgemeine Beschreibung 5.6.2. Topographische Aufnahme 5.6.3. Photogrammetrische Auswertung 5.6.4. Kartographische Arbeiten (H. BRUNNER) 5.6.5. Ergebnis Teil IIIa Glaziologische Ergebnisse der Feldarbeiten (S. MEIER) 1. Topographie und Orographie 1.1. Topographie der Eisoberfläche 1.2. Topographie des Felsuntergrundes. Eisdicken 1.3. Abflußgebiete. Gletschergrenzen 1.4. Frontlagen und -höhen 2. Eisbewegung und Deformation 2.1. Frühere Beobachtungen am Hays- und Campbell-Gletscher 2.2. Geschwindigkeitsfeld Hays-Gletscher 2.3. Querkontraktion und Längsdilatation 2.4. Zeitliche Bewegungsschwankungen 2.5. Bewegung der schwimmenden Zunge und Kalbungsrhythmus 2.6. Geschwindigkeit und Kalbungsrhythmus des Campbell-Gletschers 3. Eigenschaften des Oberflächenfirns 3.1. Temperaturen und Temperaturgradienten 3.2. Dichte, Härte, Schichtung 3.3. Vorherrschende Winde und Schneedrift 4. Komponenten des Massenhaushalts 4.1. Schneeakkumulation 1972 4.2. Schneeablation 1972/73 4.3. Eisausstoß 5. Zusammenfassung und Schlußfolgerungen Literatur Anlagen Kartenbeilage , Zusammenfassung in russischer Sprache , Text teilweise in kyrillischer Schrift , Beiträge teilweise in deutscher, teilweise in englischer Sprache
    Location: Upper compact magazine
    Location: AWI Archive
    Location: MOP - must be ordered
    Branch Library: GFZ Library
    Branch Library: AWI Library
    Branch Library: GFZ Library
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 4958-4964 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The energy shifts and widths generated in the vibrational levels of the EF, GK, and H 1Σ+g states of H2 by their nonadiabatic interactions with the electronic ground state have been calculated using ab initio wave functions. The shifts of the 44 quasibound vibronic levels of these excited states range from +0.02 to +1.00 cm−1. Along the EF progression the shifts are found to depend on vibrational kinetic energy in surprisingly good accord with the Van Vleck approximation. The calculated nonradiative decay probabilities range up to 3.3×106 s−1, and in one case the predissociation rate is as large as 39% of the radiative one. Experimental tests of these predictions are not yet available.
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 6053-6064 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The variation-perturbation method is used to calculate the nonadiabatic energy shifts of all bound vibrational levels of the B 1Σ+u and B' 1Σ+u states of H2 and D2 from the best available ab initio wave functions. In H2 the nonadiabatic energy shifts lie between extremes of −0.31 cm−1 (B,v=0) and −5.07 cm−1 (B,v=30) and, as expected, the shifts in D2 are one half as large as the ones in H2 at the same vibrational energies. The resulting nonadiabatic vibronic term values of the B state lie (approximately-equal-to)1.1±0.1 cm−1 above the experimental ones over a wide range of vibrational excitation energies, in H2 as well as in D2. This indicates that all nuclear-mass dependent contributions to the vibronic energies as well as the potential curve of the B state are now accounted for quite accurately. In the B' state the remaining discrepancies with experimental term values depend markedly on vibrational excitation, and a large part of them is nuclear mass dependent, while the remaining error of the electronic energy calculation for the B' state seems to be as small as the one for the B state.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 7461-7478 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The Born–Oppenheimer potential curves of the first two excited 1Σ+g states of H2, EF and GK, exhibit double minima which arise from avoided crossings between the electronic energy curves of the doubly excited 1σ2u configuration and of the 1Σ+g Rydberg states of the 1σg2sσg and 1σg3dσg configurations. The vibrational structures of the adiabatic electronic states are mutually coupled via strongly R-dependent off-diagonal electronic matrix elements of the d/dR and d2/dR2 operators. Furthermore the rotational structures are characterized by strong angular coupling within the complex of 3d-singlet-gerade states G 1Σ+g, I 1Πg, and J 1Δg.We have evaluated the nonadiabatic coupling functions involving the first three excited 1Σ+g states EF, GK, and H, and the I 1Πg and J 1Δg states, and have calculated their nonadiabatic rovibronic structures for the J=0–5 levels of H2, HD, and D2 up to the H(1s)+H(2s,2p) dissociation limit. The simultaneous radial and angular couplings within these five electronic states have been treated using ab initio potential curves, adiabatic corrections, and nonadiabatic coupling functions. The coupled equations have been transformed into a diabatic electronic basis and solved numerically, and the resulting eigenfunctions have been transformed back into the adiabatic basis. Energy eigenvalues, nonadiabatic energy shifts, B values, Landé g factors, band transition moments, Einstein coefficients, and radiative lifetimes have been evaluated and compared with spectroscopic results where possible. The discrepancies between observed and calculated rovibronic term values depend systematically on electronic state, vibrational energy, and isotopic mass, and their magnitudes indicate that the absolute energy errors of the ab initio potential curves amount to less than 1 cm−1 near the minima of the EF 1Σ+g and I 1Πg states, approximately 2 cm−1 in the J 1Δg state, and 5 cm−1 in the H 1Σ+g state. The nonadiabatic ab initio results have already aided spectroscopic identifications of new energy levels and they indicate that several old assignments must be discarded.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 7401-7427 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The nonadiabatic rovibronic structures of the B, B', C, and D states of H2, HD, and D2 have been calculated up to the common dissociation limit of the first three of these electronic states using the ab initio adiabatic potential curves and nonadiabatic coupling functions published recently by Wolniewicz and one of us. The homogeneous (Σ+–Σ+ and Π–Π) and heterogeneous (Σ+–Π+) interactions are treated simultaneously by numerical solution of the coupled vibrational equations for each J value from J=0 to J=6. The calculated nonadiabatic energy shifts, which show strong v- and J-dependent variations within each electronic state and which spread over approximately ±50 cm−1 for J=6 in H2, yield rovibronic structures in very good agreement with spectroscopic term values. A number of published spectroscopic assignments, including states close to the dissociation limit, must be reevaluated in the light of this calculation. The remaining energy errors are nuclear-mass dependent and are attributed to the neglected nonadiabatic interactions with the higher members of the 1Σ+u and 1Πu Rydberg series. The convergence errors of the Born–Oppenheimer energies of all four electronic states treated here appear to be at most 2 cm−1 for the highest bound vibrational states and less than 1 cm−1 for the lowest ones.
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  • 6
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Astronomy and Astrophysics 4 (1966), S. 207-244 
    ISSN: 0066-4146
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 7692-7706 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have calculated the rovibronic structures which arise from the simultaneous radial and angular couplings among the lowest nine excited 1Σ+g, 1Πg, and 1Δg states in H2, D2, and T2. Using ab initio potential curves, adiabatic corrections, and nonadiabatic coupling functions wherever possible, we have solved the coupled vibronic equations for all bound states below the 1s+2l dissociation limit up to J=5 in H2 and D2, and up to J=7 in T2. The good agreement of the bulk of the data with spectroscopic results enables us to eliminate spurious assignments in old spectroscopic work (e.g., all old assignments involving the 4s O 1Σ+g state are spurious), and to make numerous new assignments. We present updated tables of spectroscopic term values for H2 and D2. The absolute energy errors of the ab initio Born–Oppenheimer energies around the minima of the potential curves appear to be at most of the order of the radiative energy corrections ((approximately-equal-to)0.1 cm−1) in the states 1σg2sσg E and (1σu)2 F, less than 1 cm−1 in the states 3dσ G, 3s H, and 3dπ I, less than 2 cm−1 in the 4s O state, and approximately 4 cm−1 in the 4dσ P state.
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 100 (1994), S. 444-451 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: On closer examination, some of the spectroscopic assignments for the fourth excited 1∑+g state of H2 (4dσ,P) and all of the ones for the fifth state (4s,O) prove to be wrong. To aid the re-evaluation of these experimental data we have performed (i) the first accurate ab initio calculation, over a wide range of internuclear distances, of the fifth and sixth electronic 1∑+g states, i.e., of their Born–Oppenheimer electronic energy curves and adiabatic corrections, and of their nonadiabatic couplings with the lower excited electronic 1∑+g states, (ii) an improved calculation of the first three excited electronic 1∑+g states and of their mutual couplings, and (iii) the first calculation of relativistic corrections for the first two of these excited states, EF and GK, at the minima of their double-well potential energy functions. We have found that the electronic energy curves of the pairs of singlet ndσ and ns states (n=3, 4), unlike the triplet 3dσ and 3s states, cross each other at internuclear distances which are much smaller than their equilibrium R values and with off-diagonal electronic energies that are at least 2 orders of magnitude smaller than the diabatic coupling energies at the avoided crossings of the corresponding triplet states.
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 88 (1988), S. 3861-3870 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The B, B', C, and D states of H2 are represented over wide ranges of the internuclear distance R by considerably more flexible electronic wave functions than the ones previously employed by Kolos, Rychlewski, and one of us (L.W.). These are used to compute the nonadiabatic coupling matrix elements for the homogeneous B'–B and D–C and the heterogeneous C–B, C–B', D–B, and D–B' interactions over a wide range of R values. The adiabatic potential curves obtained from the new electronic wave functions yield vibrational term values which, for the v=0 levels, lie within 0.6 to 2.2 cm−1 of the experimental ones in these four electronic states of H2. After subtracting the nuclear-mass-dependent contributions to these ab initio errors, which can be estimated by comparing H2 with D2, the remaining electronic errors near the equilibrium internuclear distances of these electronic states are approximately 0.3 cm−1 (C and D state) and 1 cm−1 (B and B' state). In the C, D, and B' states this represents improvements by 0.7, 6, and 8 cm−1, respectively, over the previous ab initio values.
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 1205-1211 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Motivated by the observations of tunneling resonances in the rotation–vibration structures of the EF 1Σ+g double-minimum states of H2 and D2 we calculate the resonant tunneling frequencies of these states with a semiclassical formula, using accurate ab initio potential functions with appropriate adiabatic and rotational corrections. Good agreement is obtained with the corresponding two-state interaction energies which describe these tunneling resonances and which are evaluated by fitting either the experimental term values or the accurate quantum mechanical energy eigenvalues of the double-minimum oscillator.
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