Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
89 (1988), S. 20-24
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The internuclear dependence of the CO (A 1 π– X 1 Σ+ ) transition moment has been obtained for the range 1.0〈r¯〈1.8 A(ring). This was done by making laser induced fluorescence measurements on highly vibrationally excited CO. These data were jointly fit with fluorescence lifetime data from a previous study done by Field et al. The second-order fit obtained was 〈Re(r¯)〉 =10.57(41)[1−1.177(22)r¯+0.350(13)r¯2] D. This fit provides a good description of the transition moment function in that it quantitatively fits the fluorescence branching ratio data and lifetime data and agrees with the qualitative observation of CO(A–X) transition strengths.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.455507
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