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Visible light photopolymerization employing 2,4-diiodo-6-butoxy-3-fluorone and tetraorganylborate salts as photoinitiators (1996)

Sarker, Ananda M. ; Polykarpov, Alexander Y. ; De Raaff, Anita M. ; [et al.]

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 2817-2824

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ISSN: 0887-624X

Keywords: visible light photopolymerization ; tetraorganylborates ; fluorone dyes ; acrylic monomers ; Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Several new tetraorganylborate salts have been synthesized and tested as coinitiators with 2,4-diiodo-6-butoxy-3-fluorone (DIBF) for the photopolymerization of acrylic monomer mixtures. The rate of photopolymerization has been found to be a function of chemical structure of the borates. Stability, solubility, and reactivity of these borates as coinitiators for photopolymerization have been investigated. Diphenyldialkylborates have been found to be the best among the tested coinitiators. © 1996 John Wiley & Sons, Inc.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

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