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  • 1
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    Hage, S., Galy, V. V., Cartigny, M. J. B., Acikalin, S., Clare, M. A., Grocke, D. R., Hilton, R. G., Hunt, J. E., Lintern, D. G., McGhee, C. A., Parsons, D. R., Stacey, C. D., Sumner, E. J., & Talling, P. J. (2020). Efficient preservation of young terrestrial organic carbon in sandy turbidity-current deposits. Geology, 48(9), 882-887.
    Publication Date: 2022-10-05
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Hage, S., Galy, V. V., Cartigny, M. J. B., Acikalin, S., Clare, M. A., Grocke, D. R., Hilton, R. G., Hunt, J. E., Lintern, D. G., McGhee, C. A., Parsons, D. R., Stacey, C. D., Sumner, E. J., & Talling, P. J. Efficient preservation of young terrestrial organic carbon in sandy turbidity-current deposits. Geology, 48(9), (2020): 882-887, doi:10.1130/G47320.1.
    Description: Burial of terrestrial biospheric particulate organic carbon in marine sediments removes CO2 from the atmosphere, regulating climate over geologic time scales. Rivers deliver terrestrial organic carbon to the sea, while turbidity currents transport river sediment further offshore. Previous studies have suggested that most organic carbon resides in muddy marine sediment. However, turbidity currents can carry a significant component of coarser sediment, which is commonly assumed to be organic carbon poor. Here, using data from a Canadian fjord, we show that young woody debris can be rapidly buried in sandy layers of turbidity current deposits (turbidites). These layers have organic carbon contents 10× higher than the overlying mud layer, and overall, woody debris makes up 〉70% of the organic carbon preserved in the deposits. Burial of woody debris in sands overlain by mud caps reduces their exposure to oxygen, increasing organic carbon burial efficiency. Sandy turbidity current channels are common in fjords and the deep sea; hence we suggest that previous global organic carbon burial budgets may have been underestimated.
    Description: We thank C. Johnson, M. Lardie, A. Gagnon, A. McNichol, and the NOSAMS (National Ocean Sciences Accelerator Mass Spectrometry) team (Woods Hole Oceanographic Institution [WHOI], Massachusetts, USA) for their help with ramped oxidation system and isotopes. We thank the captain and crew of CCGS Vector. Support was provided by UK Natural Environment Research Council (NERC) grants NE/M007138/1 (to Cartigny) and NE/L013142/1 (to Talling), NE/P005780/1 and NE/P009190/1 (to Clare); a Royal Society Research Fellowship (to Cartigny); an International Association of Sedimentologists Postgraduate Grant and National Oceanography Centre Southampton–WHOI exchange program funds (to Hage); an independent study award from WHOI (to Galy); the Climate Linked Atlantic Sector Science (CLASS) program (NERC grant NE/R015953/1); and the European Research Council under the European Union’s Horizon 2020 research and innovation program (Grant 725955, to Parsons). We thank François Baudin, Xingqian Cui, editor James Schmitt, and three anonymous reviewers.
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Hage, S., Galy, V., Cartigny, M., Heerema, C., Heijnen, M., Acikalin, S., Clare, M., Giesbrecht, I., Gröcke, D., Hendry, A., Hilton, R., Hubbard, S., Hunt, J., Lintern, D., McGhee, C., Parsons, D., Pope, E., Stacey, C., Sumner, E., Tank, S., & Talling, P. Turbidity currents can dictate organic carbon fluxes across river‐fed fjords: an example from Bute Inlet (BC, Canada). Journal of Geophysical Research: Biogeosciences, 127(6), (2022): e2022JG006824, https://doi.org/10.1029/2022jg006824.
    Description: The delivery and burial of terrestrial particulate organic carbon (OC) in marine sediments is important to quantify, because this OC is a food resource for benthic communities, and if buried it may lower the concentrations of atmospheric CO2 over geologic timescales. Analysis of sediment cores has previously shown that fjords are hotspots for OC burial. Fjords can contain complex networks of submarine channels formed by seafloor sediment flows, called turbidity currents. However, the burial efficiency and distribution of OC by turbidity currents in river-fed fjords had not been investigated previously. Here, we determine OC distribution and burial efficiency across a turbidity current system within Bute Inlet, a fjord in western Canada. We show that 62% ± 10% of the OC supplied by the two river sources is buried across the fjord surficial (30–200 cm) sediment. The sandy subenvironments (channel and lobe) contain 63% ± 14% of the annual terrestrial OC burial in the fjord. In contrast, the muddy subenvironments (overbank and distal basin) contain the remaining 37% ± 14%. OC in the channel, lobe, and overbank exclusively comprises terrestrial OC sourced from rivers. When normalized by the fjord’s surface area, at least 3 times more terrestrial OC is buried in Bute Inlet, compared to the muddy parts of other fjords previously studied. Although the long-term (〉100 years) preservation of this OC is still to be fully understood, turbidity currents in fjords appear to be efficient at storing OC supplied by rivers in their near-surface deposits.
    Description: S.H. acknowledges funding by the IAS postgraduate grant scheme, a Research Development funds offered by Durham University, and the NOCS/WHOI exchange program. S.H. has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement no. 899546. The field campaign and geochemical analyses were supported by Natural Environment Research Council grants NE/M007138/1, NE/W30601/1, NE/N012798/1, NE/K011480/1 and NE/M017540/1. M.J.B.C. was funded by a Royal Society Research Fellowship (DHF\R1\180166). M.A.C. was supported by the U.K. National Capability NERC CLASS program (NE/R015953/1) and NERC grants (NE/P009190/1 and NE/P005780/1). C.J.H. and M.S.H. were funded by the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement no. 721403 - ITN SLATE. E.L.P. was supported by a Leverhulme Early Career Fellowship (ECF-2018-267).
    Keywords: Fjords ; Organic carbon ; Sediment ; Submarine channel ; Carbon burial ; Rivers
    Repository Name: Woods Hole Open Access Server
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 43 (1978), S. 3048-3052 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of medicinal chemistry 14 (1971), S. 1118-1120 
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 7637-7655 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The theory of the spin-coupled (SC) wave function with core-valence separation, in which the core electrons are confined to a closed shell of doubly-occupied orbitals and the valence electrons are described with the complete set of features of the SC formalism, is developed to produce an efficient approach which makes possible its fully variational determination. The simultaneous optimization of the core orbitals, valence orbitals, and spin-coupling coefficients is achieved through a second-order nonlinear elimination constrained minimization algorithm which exhibits excellent convergence properties. It is no longer necessary to introduce an ad hoc preselection of core and valence orbitals−this is carried out by the minimization procedure itself which makes an optimum choice from a variational point of view. The only important item left to personal judgment is the selection of the number of core and valence electrons in the problem under investigation. Simplifications such as "freezing'' of a part of the core orbitals are discussed alongside with the verification of the theoretical work and program code by emulating, under an appropriately modified set of constraints, the generalized valence-bond (GVB) wave function with perfect pairing and strong-orthogonality restrictions. It is demonstrated that it is possible, similar to the Hartree–Fock (HF) method, to transform the core orbitals into canonical form and to associate with each one of them an energetical quantity analogous to the HF orbital energy. The essential features of the approach are illustrated by a SC study of the process H2CO(1A1)→CH2(X˜ 3B1)+O(3P), involving the breaking of the C(large-closed-square)O double bond. The results prove that only a fully variational SC wave function with core-valence separation is capable of providing a uniform description of the change in the physical properties of the system upon dissociation, which can be achieved by including in the SC part of the wave function just the four electrons immediately involved in the carbon–oxygen double bond.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 4895-4902 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Transition dipole moments between five low-lying adiabatic states of CO, X 1Σ+, A 1Π, 2 1Σ+ (B 1Σ+ and D' 1Σ+), 3 1Σ+ (C 1Σ+ and C' 1Σ+) and 2 1Π (E 1Π), have been obtained. Ab initio calculations of the electronic energies and wave functions for these states have been reported by us previously. The calculated oscillator strengths and radiative lifetimes are compared with various measurements of these quantities. These comparisons are complicated by the large discrepancies among the experimental measurements, apparent even in the most recent studies.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Boston, MA, USA : Blackwell Science Inc
    Restoration ecology 8 (2000), S. 0 
    ISSN: 1526-100X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: South Park is a high-elevation, semi-arid, treeless intermountain basin in central Colorado. A few extreme rich fens occur on the western margin and in the center of South Park where regional and local groundwater flow systems discharge to the ground surface. Over the past 40 years there has been extensive peat mining in these fens, but restoration methods have yet to be developed and successfully applied. The first part of this study compared the naturally reestablished vegetation on six mined peatlands with six pristine sites, while the second part of the study tested different revegetation techniques in 27 plots with varying depths to the water table. The six mined sites had only 30 plant species as compared with 122 species in the unmined sites; 43% of the species in the mined sites were not present in the undisturbed fens. Even after 40 years the sedges and willows that dominate the undisturbed sites were largely absent on the mined sites. The revegetation experiments seeded eight species, transplanted Carex aquatilis (water sedge) seedlings, transplanted rhizomes from six species, and transplanted four species of willow cuttings. Of the eight species seeded, only Triglochin maritima (arrowgrass) germinated and established seedlings. C. aquatilis seedlings, rhizome transplants of C. aquatilis, Kobresia simpliciuscula (elk sedge), and Juncus arcticus (arctic rush), and willow cuttings all had differing patterns of survival with respect to the annual maximum height of the water table. These results indicate that the dominant species can be successfully reintroduced to mined surfaces with the appropriate hydrologic conditions, but human intervention will be necessary to rapidly re-establish these species. The slow rate of peat accumulation means that restoration of the mined fens will require hundreds, if not thousands, of years.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 56 (1990), S. 805-807 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Frequency modulation spectroscopy through a single-mode optical fiber has been demonstrated for monitoring H2O vapor at 7665 cm−1. Using a 2.5 mW distributed feedback laser and 100 m of optical fiber, a minimum detectable absorption of 5×10−7 was achieved. To obtain this sensitivity limit, very large spurious signals and technical noise were suppressed using a dual-channel detection scheme.
    Type of Medium: Electronic Resource
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