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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The formation chemistry and growth dynamics of thin-film CuInSe2 grown by physical vapor deposition have been considered along the reaction path leading from the CuxSe:CuInSe2 two-phase region to single-phase CuInSe2. The (Cu2Se)β(CuInSe2)1−β (0〈β≤1) mixed-phase precursor is created in a manner consistent with a liquid-phase assisted growth process. At substrate temperatures above 500 °C and in the presence of excess Se, the film structure is columnar through the film thickness with column diameters in the range of 2.0–5.0 μm. Films deposited on glass are described as highly oriented with nearly exclusive (112) crystalline orientation. CuInSe2:CuxSe phase separation is identified and occurs primarily normal to the substrate plane at free surfaces. Single-phase CuInSe2 is created by the conversion of the CuxSe into CuInSe2 upon exposure to In and Se activity. Noninterrupted columnar growth continues at substrate temperatures above 500 °C. The addition of In in excess of that required for conversion produces an In-rich near-surface region with a CuIn3Se5 surface chemistry. A model is developed that describes the growth process. The model provides a vision for the production of thin-film CuInSe2 in industrial scale systems. Photovoltaic devices incorporating Ga with total-area efficiencies of 14.4%–16.4% have been produced by this process and variations on this process. © 1995 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 1749-1753 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The magnetic properties of rf sputtered amorphous (Co93Zr7)100−xTbx thin films were investigated as a function of Tb content for 0≤x≤2 by transverse biased initial susceptibility measurements. The deposition was performed in a magnetic field. This films exhibit a very well-defined in-plane anisotropy with negligible long-range fluctuations and a small coercive field Hc, in accordance with the experimental data. The overall variations of the transverse susceptibility are related to the ripple, and the variations of the structure factor S with composition was measured. The local anisotropy Kloc, deduced from S, increases with the increasing amount of Tb in the layers. The results are discussed in terms of the single-ion anisotropy of the rare earth.
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  • 3
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: For thin films with very well defined uniaxial anisotropy, initial permeability spectra in the hard direction may be well described by Landau–Lifshitz theory that, in the low frequency range, is reduced to μi=4πMs/Hk. But the switching process of the magnetization becomes more complex when it is dominated by local variations of the anisotropy, what is known as magnetization ripple. Then, initial permeability at low frequency may be expressed as μi=4πMs/Heff. Here, effective field Heff is, from ripple theory: Heff=Hk(1+b+c), the terms b and c being additional anisotropy fields due to short and long range magnetization fluctuations. Measurements of Hk, b, and c can be obtained from the transverse bias permeability that has been measured along easy and hard axis by transverse Kerr effect. We obtain values of b+c between 0.04 and 0.30, what imply a reduction of permeability between 4% and 30% due to the dispersion of the anisotropy. Saturation magnetization was measured using a VSM and also with a computer aided hysteresismeter. Then, initial permeability was measured along hard axis using an inductive system previously described. © 1996 American Institute of Physics.
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  • 4
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The composition and temperature dependence of electrical resistivity were studied for a series of amorphous (Co93Zr7)100−xNdx for x〈3.4 and for a temperature range between 77 and 300 K. The films were deposited by rf sputtering. Measurements of electrical resistivity were performed by the standard four probe technique with ac currents of 10 mA. The rate of heating and cooling was 1 K/min. The electrical resistivity is very sensitive to the presence of Nd ions, as the resistivity clearly increases with a very slight increase of Nd content. The temperature dependence of resistivity does not obey the T2 law predicted by the diffraction model as proposed by Meisel and Cote but follows very nicely the law ρ(T)=aT3/2−bT+c, a result also found for amorphous Gd–Co. The first term corresponds to the electron scattering from the magnetic spin and the second term to the electron scattering from the disordered configuration of atomic potentials. © 1996 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 3168-3174 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The induced in-plane and local magnetic anisotropies of rf sputtered (Co93Zr7)100−xREx thin films were investigated as a function of RE content for RE=Pr, Nd, and Tb by transverse biased initial susceptibility measurements at both film/air and glass/film interfaces. The deposition was performed in a magnetic field. The films exhibit a very well defined in-plane anisotropy with negligible long-range fluctuations and a small coercive field Hc, in accordance with the experimental data. The overall variations of the transverse susceptibility are related to the ripple. The variations of the local anisotropy with composition were measured. Both the induced anisotropy Ku and the local anisotropy Kloc increase with the increasing amount of RE in the layers. A clear relationship between Ku and Kloc could be established. The results are discussed in terms of the single-ion anisotropy of the rare earth. While the value of Ku is the same at both interfaces, the ripple constants were found to be slightly different. This last result is believed to be related to some local defects, the origin of which is also suggested. Also the coercive force is discussed and explained in terms of a theoretical model. © 1996 American Institute of Physics.
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Transverse biased initial susceptibility (TBIS) measurements were made using a magneto-optical Kerr effect system on samples that exhibited an in-plane and a perpendicular anisotropy. A change in the slope of both the inverse transverse susceptibility and the hysteresis loop is observed at a certain value of the applied in-plane field Hs. At values of the applied field higher than Hs the magnetization lies in the plane of the film; at values lower than Hs an out-of-plane component appears. By performing TBIS measurements we can also detect different micromagnetic phases magnetically uncoupled with different values of the anisotropy field. The occurrence of a downwards curvature in the inverse susceptibility when the dc field is applied along the hard axis together with the multiple minima when the dc field is applied along the easy axis can be explained by the existence of weakly coupled micromagnetic phases. © 1996 American Institute of Physics.
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  • 7
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Experimental characterization of magnetic anisotropy, coercive field, and anisotropy dispersion of sputtered Fe/CoNbZr and Fe/Ag/CoNbZr sandwiches were carried out by transverse biased initial susceptibility (TBIS) measurements with a magneto-optic Kerr effect at both film/air and glass/film interfaces. Three different behaviors have been observed depending on the range of magnetization fluctuation. The results indicate that Fe grains play a fundamental role in the type of the dispersion (long range or short range). The results obtained from the coercive field and from x-ray diffractograms agree with those obtained by TBIS. © 1996 American Institute of Physics.
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  • 8
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: X-ray photoemission spectroscopy (XPS) and positron annihilation spectroscopy (PAS) have been used to characterize the surface versus bulk composition, electronic, and physical structure of polycrystalline Cu(In,Ga)Se2 thin-film interfaces. Angle-resolved high-resolution photoemission measurements on the valence-band electronic structure and Cu 2p, In 3d, Ga 2p, and Se 3d core lines were used to evaluate the surface and near surface chemistry of CuInSe2 and Cu(In,Ga)Se2 device grade thin films. XPS compositional depth profiles were also acquired from the near surface region. PAS was used as a nondestructive, depth-sensitive probe for open-volume-type defects. Results of these measurements are related to device efficiencies to show the effects of compositional variations and defect concentrations in the near surface region on device performance. © 1995 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 2492-2501 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We present and apply an approximate general theory for the effects of the direct interactions on the translational and rotational diffusion coefficients of a nonspherical Brownian particle interacting with other spherical particles diffusing around it. These results are specialized to a system formed by a charged axially-symmetric macroparticle that diffuses in an ionic solution, whose static properties are described within the Debye-Hückel approximation. In particular, we calculate the static friction coefficients of a Brownian point-dipole embedded in a hard-sphere, and of a charged hard-ellipsoidal tracer particle.
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 954-959 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The effect of asymmetric charge distribution on the structural properties of a lamellar system of ionic layers was determined with the use of the hypernetted chain theory. Due to electrostatic interaction and positional correlations between ions in all different layers, there appear layer pairs attractive forces which enhance when the ionic charge and concentration per layer is increased or when the distance of separation in reduced. The innermost layer pairs show the strongest attractive interaction due to an increased enhancement of ionic correlations. Asymmetry in the ionic concentration in the normal direction to the planes and moderate layers separation, h, produce a nonmonotonous pressure curve as a function of h for the more exterior layer pairs whereas at longer separations this pressure shows the universal asymptotic power law of correlated charge fluctuations of a simple two layer system, P∼−1/h3. © 2000 American Institute of Physics.
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