ISSN:
1588-2780
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Energy, Environment Protection, Nuclear Power Engineering
Notes:
Abstract The57Fe Mössbauer spectra of substituted pentacyanoferrate /II/ complexes [/CN/5 FeII L]3− have been obtained for L=adenine, guanine, purine, caffeine, ethylene sulphide, dimethyl sulphoxide, and ammonia. The Mössbauer parameters are utilized to classify the various ligands according to their σ and π bonding abilities. A linear correlation between the Mössbauer isomer shift and the tetragonal distortion caused by the ligand L is proposed. Comparison between this linear correlation and the approximative method of Wentworth and Piper1 is made.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02163975
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