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An expression for local composition in polymer-solution thermodynamics (1982)

Canovas, A. A. ; Rubio, R. G. ; Renuncio, J. A. R.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 783-791

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ISSN: 0098-1273

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: An expression for local composition which describes nonrandom interactions between unlike molecules in polymer solutions is proposed. This expression makes the nonrandom model compatible with the one-fluid hypothesis and satisfies the limits of randomness when experimental conditions evolve in such a way. Data on several binary systems are studied using this model which represents simultaneously activity and heat-of-mixing data.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1982.180200501

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