ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
(C6H5)2SeCl2 and anhydrous NH3 react in methylene chloride giving the salt-like bis-[diphenylselenide]-nitride chloride, [ø 2Se=N=Se ø2]X (X = Cl), from which, by metathetic interactions, salts with X = Br, N3, IO4, 1/3 [FeIII(CN)6] have been prepared. Solutions of these salts in methanol exhibit good electrical conductivities.
Notes:
(C6H5)2SeCl2 und gasförmiges NH3 reagieren in Methylenchlorid zu dem salzartig gebauten Bis-[diphenylselenid]-nitrid-chlorid. Durch doppelte Umsetzungen wurden daraus das Bromid, Azid, Perjodat und Hexacyanoferrat (III) hergestellt. Die Lösungen der Salze in Methanol zeigen gute elektrische Leitfähigkeit.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19663480309
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