ALBERT

Description: Measurements of global and diffuse photosynthetically active radiation (PAR) have been carried out on the island of Lampedusa, in the central Mediterranean Sea, since 2002. PAR is derived from observations made with multi-filter rotating shadowband radiometers (MFRSRs) by comparison with a freshly calibrated PAR sensor and by relying on the on-site Langley plots. In this way, a long-term calibrated record covering the period 2002–2016 is obtained and is presented in this work. The monthly mean global PAR peaks in June, with about 160 W m−2, while the diffuse PAR reaches 60 W m−2 in spring or summer. The global PAR displays a clear annual cycle with a semi amplitude of about 52 W m−2. The diffuse PAR annual cycle has a semi amplitude of about 12 W m−2. A simple method to retrieve the cloud-free PAR global and diffuse irradiances in days characterized by partly cloudy conditions has been implemented and applied to the dataset. This method allows retrieval of the cloud-free evolution of PAR and calculation of the cloud radiative effect, CRE, for downwelling PAR. The cloud-free monthly mean global PAR reaches 175 W m−2 in summer, while the diffuse PAR peaks at about 40 W m−2. The cloud radiative effect, CRE, on global and diffuse PAR is calculated as the difference between all-sky and cloud-free measurements. The annual average CRE is about −14.7 W m−2 for the global PAR and +8.1 W m−2 for the diffuse PAR. The smallest CRE is observed in July, due to the high cloud-free condition frequency. Maxima (negative for the global, and positive for the diffuse component) occur in March–April and in October, due to the combination of elevated PAR irradiances and high occurrence of cloudy conditions. Summer clouds appear to be characterized by a low frequency of occurrence, low altitude, and low optical thickness, possibly linked to the peculiar marine boundary layer structure. These properties also contribute to produce small radiative effects on PAR in summer. The cloud radiative effect has been deseasonalized to remove the influence of annual irradiance variations. The monthly mean normalized CRE for global PAR can be well represented by a multi-linear regression with respect to monthly cloud fraction, cloud top pressure, and cloud optical thickness, as determined from satellite MODIS observations. The behaviour of the normalized CRE for diffuse PAR can not be satisfactorily described by a simple multi-linear model with respect to the cloud properties, due to its non-linear dependency, in particular on the cloud optical depth. The analysis suggests that about 77 % of the global PAR interannual variability may be ascribed to cloud variability in winter.

Description: Particulate matter with aerodynamic diameters lower than 10 µm, (PM10) aerosol samples were collected during summer 2013 within the framework of the Chemistry and Aerosol Mediterranean Experiment (ChArMEx) at two sites located north (Capo Granitola) and south (Lampedusa Island), respectively, of the main Mediterranean shipping route in the Straight of Sicily. The PM10 samples were collected with 12 h time resolutions at both sites. Selected metals, main anions, cations and elemental and organic carbon were determined. The evolution of soluble V and Ni concentrations (typical markers of heavy fuel oil combustion) was related to meteorology and ship traffic intensity in the Straight of Sicily, using a high-resolution regional model for calculation of back trajectories. Elevated concentration of V and Ni at Capo Granitola and Lampedusa are found to correspond with air masses from the Straight of Sicily and coincidences between trajectories and positions of large ships; the vertical structure of the planetary boundary layer also appears to play a role, with high V values associated with strong inversions and a stable boundary layer. The V concentration was generally lower at Lampedusa than at Capo Granitola V, where it reached a peak value of 40 ng m−3. Concentrations of rare earth elements (REEs), La and Ce in particular, were used to identify possible contributions from refineries, whose emissions are also characterized by elevated V and Ni amounts; refinery emissions are expected to display high La ∕ Ce and La ∕ V ratios due to the use of La in the fluid catalytic converter systems. In general, low La ∕ Ce and La ∕ V ratios were observed in the PM samples. The combination of the analyses based on chemical markers, air mass trajectories and ship routes allows us to unambiguously identify the large role of the ship source in the Straight of Sicily. Based on the sampled aerosols, ratios of the main aerosol species arising from ship emission with respect to V were estimated with the aim of deriving a lower limit for the total ship contribution to PM10. The estimated minimum ship emission contributions to PM10 were 2.0 µg m−3 at Lampedusa and 3.0 µg m−3 at Capo Granitola, corresponding with 11 and 8.6 % of PM10, respectively.

Description: Measurements of global and diffuse photosynthetically active radiation (PAR) have been carried out on the island of Lampedusa, in the central Mediterranean Sea, since 2002. PAR is derived from observations made with multi filter rotating shadowband radiometers (MFRSRs) by comparison with a freshly calibrated PAR sensor and by relying on the on-site Langley plots. In this way, a long-term calibrated record covering the period 2002–2016 is obtained and is presented in this work. The monthly mean global PAR peaks in June, with about 160 W m−2, while the diffuse PAR reaches 60 W m−2 in some cases in spring or summer. The global PAR displays a clear annual cycle with a semi amplitude of about 52 W m−2. The diffuse PAR annual cycle has a semi amplitude of about 12 W m−2 (about 23 % of the annual mean value). The diffuse PAR is about 39 % of the global, with a marked seasonal variation, between about 25–30 % in winter and about 50 % in summer. A simple method to retrieve the cloud-free PAR global and diffuse irradiances in days characterized by partly cloudy conditions has been implemented and applied to the dataset. This method allows to retrieve the cloud-free evolution of PAR, and to calculate the cloud radiative effect. CRE, for downwelling PAR. The cloud-free monthly mean global PAR reaches 175 W m−2 in summer, and the diffuse PAR about 40 W m−2. The annual semi amplitudes are similar for all-sky and cloud-free data. The diffuse PAR for the cloud-free cases is about 24 % of the global. The cloud radiative effect, CRE, on global and diffuse PAR is calculated as the difference between all-sky and cloud-free measurements. The average CRE is about −14.7 W m−2 for the global, and +8.1 W m−2 for the diffuse PAR. The smallest CRE is observed in July, due to the high cloud-free conditions frequency. Maxima (negative for the global, and positive for the diffuse component) occur in March–April and in October, due to the combination of elevated PAR irradiances and high occurrence of cloudy conditions. Largest monthly mean values of CRE are at about −31 W m−2 for the global (April 2007), and +18 W m−2 for the diffuse component (April 2010). Summer clouds appear to be characterized by a low frequency of occurrence, low altitude, and low optical thickness, possibly linked to the peculiar marine boundary layer structure. These properties also contribute to produce small radiative effects on PAR in summer. The cloud radiative effect has been de-seasonalized to remove the influence of annual irradiance variations. The monthly mean normalized CRE for global PAR shows a statistically significant high correlation with monthly cloud fraction, cloud top pressure, and cloud optical thickness, as determined from satellite MODIS observations. The normalized CRE for diffuse PAR show lower correlations, although still statistically significant, with cloud fraction and cloud top pressure, while displays a limited correlation with cloud optical thickness. Cloud fraction seems to be the most relevant parameter driving the cloud radiative effects. Normalized CRE data have been de-seasonalized and related with variations of the de-seasonalized PAR. A statistically significant correlation is found between the de-seasonalized PAR and the de-seasonalized normalized CRE. This correlation is seasonally dependent, and suggests that about 77 % of the global PAR interannual variability may be ascribed to clouds variability in winter.

Description: Measurements of downwelling shortwave (SW) and longwave (LW) irradiance were carried out on an oceanographic buoy close to the island of Lampedusa (Italy), in the central Mediterranean Sea. Irradiance measurements on the buoy were acquired at high time resolution together with the radiometer pitch and roll angles. The measurements carried out during 2016 have been compared with ground-based observations made at the Lampedusa Atmospheric Observatory, about 15 km northeast of the buoy. The radiometers were compared before and after deployment on the buoy and are traceable to the World Radiometric Reference scale. The SW measurements were corrected for the thermal offset. A small bias (measurements over the sea are smaller than on land) of about −2 W m−2 is found in the daily mean SW, and a moderate bias of +6.2 W m−2 (irradiance over the sea is larger than on land) is found in the LW. Similar biases are found when instantaneous measurements obtained with horizontal radiometers, clean domes, and cloud-free conditions are selected, suggesting that impacts of the moving platform and poor dome cleaning are minor at this site. The effect of the mean tilt angle was also investigated. Deviations in the hourly mean SW irradiance are on the order of 20% for a mean offset of 4° with respect to the solar zenith angle; the effect of tilt angle on LW irradiance appears to be negligible. Radiative transfer calculations show that the observed biases may be ascribed to the differences in the instrument altitude (through radiation absorption, scattering, and emission by the atmospheric constituents in the lowest atmospheric layers) and in the SW surface albedo.