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  • 1
    Monograph available for loan
    Monograph available for loan
    Englewood Cliffs, NJ : Prentice-Hall
    Call number: G 8769
    Type of Medium: Monograph available for loan
    Pages: X, 481 S. : graph. Darst.
    ISBN: 0137743734
    Location: Upper compact magazine
    Branch Library: GFZ Library
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 63 (1959), S. 1566-1569 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 3694-3704 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the viscosity of four binary mixtures near their consolute points: (1) methanol+cyclohexane, (2) isobutyric acid+water, (3) nitroethane+3-methylpentane, and (4) 2-butoxyethanol+water. The viscosity data are consistent with the power-law divergence: η∼||T−Tc||−y, with an apparent viscosity exponent in the range 0.0404〈y〈0.0444. Recent theoretical estimates for y are near 0.032, which is outside the experimental range. The value of y is independent of whether the critical point is an upper or a lower consolute point and of whether the approach toward Tc is at constant pressure or at constant volume. Our torsion oscillator viscometer is unique in its simultaneous low frequency (∼1 Hz) and low shear rate (∼0.1 s−1), allowing its use close to the critical point before encountering non-Newtonian fluid behavior associated with critical slowing down. Nevertheless, we find quantitative evidence for viscoelasticity near the critical point.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 7761-7765 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The flow of the microemulsion dioctylsulfosuccinate (AOT)/decane/water through 0.1 and 1.0 μm diameter pores was studied for water droplet volume fractions ranging from 0 to 0.5. The viscosity of these microemulsions, as measured in a capillary viscometer with a bore of ≈1 mm diameter, exceeds by as much as a factor of 4 theoretical predictions of the viscosity of suspensions of hard or liquid spheres. If droplet clustering causes this viscosity enhancement, then flow of the microemulsions through pores with diameter small compared to the characteristic cluster size should display a large finite-size effect. The apparent viscosity of the microemulsions in pores differed from the viscosity measured in the capillary viscometer by less than 40% for 0.1 μm diameter pores and by less than 8% for 1.0 μm diameter pores. These differences are of the same scale as estimates of two effects: adsorption of droplets on the pore wall and the enhanced flow of suspensions near a wall. The absence of larger finite-size effects implies that clustering of droplets on length scales of 0.1 μm or larger does not contribute substantially to the microemulsion viscosity.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 4665-4670 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The frequency dependence of the real and imaginary parts of a nickel oscillator's transfer function is described over 3 decades in frequency by the use of simple expressions. These expressions incorporate only the resonance frequency ω0, the quality factor Q, and a characteristic exponent β determined by a single measurement of creep. They are based on the ansatz φ(ω)=Q−1(ω/ω0)−β, where φ is the imaginary part of the spring constant. Over a 100 K range of temperature T, the exponent β(approximately-equal-to)0.18 was constant even though Q(T) changed by a factor of 8. These expressions are potentially useful for accurately describing a mechanical oscillator whose transfer function must be modeled at frequencies far below ω0. Examples include accelerometers based on a flexure element and suspensions for interferometric gravitational wave detectors.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 57 (1986), S. 1667-1672 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We describe a torsion-oscillator viscometer whose low frequency (0.5 Hz) and very low shear rate (0.05 s−1) are required for measurements of shear sensitive fluids such as microemulsions, polymer melts and solutions gels, and liquid mixtures near critical points. The viscometer has a resolution of 0.2% when used with liquid samples and a resolution of 0.4% when used with a dense gaseous sample. The viscometer operates under computer control and is compatible with submillikelvin temperature control.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 8 (1996), S. 1464-1475 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Just above the liquid-vapor critical point, a fluid's large compressibility causes a stable stratification in which the density varies by as much as 10% in 1 cm. This stratification supports internal gravity waves which we observed with an oscillator immersed in a near-critical xenon sample. We found the number and frequencies of the observable modes depended on the sample cell's orientation, with only two modes seen in the horizontal cell. The frequencies of the two modes had different temperature dependences: with decreasing temperature, the higher frequency increased monotonically from 0.7 to 2.8 Hz, but the lower frequency varied nonmonotonically, with a maximum of 1.0 Hz at 20 mK above the critical temperature. These temperature dependences continued to 20 mK below the critical temperature, where the xenon was separated into liquid and vapor phases. We calculated these two frequencies by solving the eigenvalue problem of internal waves in a box containing a stratified fluid. The fluid's density profile was obtained from xenon's equation of state. The calculated and measured frequencies agree to within 15%. Analytical calculations based on simple approximations of the density profile provide insight into the observed temperature dependences. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 62 (1991), S. 527-529 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Mixing without excessive heating is sometimes needed for temperature-sensitive fluids. We modified an inexpensive low-frequency electronic filter based on a mechanical resonator to produce a compact (16 mm) and low-power (1–3 mW) mixer for low viscosity fluids. Tests made in air and methanol at room temperature and in fluoroform near its critical point are compared against the predictions of an electromechanical model.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 1513-1518 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the apparent critical exponent y characterizing the divergence of the viscosity η∝(T−Tc)−y near the liquid–liquid critical point of the mixture polystyrene in diethyl malonate. The data span the range in reduced temperature of 10−4〈(T−Tc)/Tc〈10−1. The sample was prepared from the same materials used by Gruner et al. in their capillary viscometer [Macromolecules 23, 510 (1990)]; however our torsion oscillator viscometer had a shear rate 80 times lower. This increased the range of reduced temperatures where shear effects could be neglected. In spite of the large reduction in shear rate and the different viscometry technique, the parameters fitted to our data and those of Gruner et al. are in agreement. For this polymer solution, y is in the range 0.028±0.003, close to recent results for two other polymer solutions measured in capillary viscometers. However, it is significantly smaller than the exponent for pure fluids (0.041± 0.001) and simple binary mixtures (0.042±0.002). It appears that polymer solutions are in a dynamic universality class different from that of simpler fluids.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 71 (1967), S. 3352-3354 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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