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  • 1
    Publication Date: 2020-05-15
    Description: Petroleum and its related products pose a serious pollution risk to the world’s seas and require a simple, rapid detection method. This is a difficult task if the pollution is under the water surface. One common approach to oil detection is excitation-emission spectroscopy (EEMs) of seawater exposed to oil for analyzing the fluorometric index (FIo/w) as a potential indicator of oil presence in the marine environment. In this paper, FIo/w was determined for both natural seawater and samples of the same water, but exposed to a relatively small portion of oil. The water samples were collected from the coastal and port waters of the Gdynia region (Southern Baltic Sea) from five stations, four times at two-week intervals. FIo/w indicates the changes between seawater sampled from the marine environment and the same seawater polluted with oil substances. Moreover, the obtained FIo/w values do not depend on the point and time of sampling. In all cases of seawater exposed to oil, significantly higher FIo/w values were observed than for unpolluted seawater. Moreover, the detection of oil by analyzing the value of FIo/w is efficient if the oil-to-water weight ratio is close to or above 5 × 10−6.
    Electronic ISSN: 2071-1050
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 2
    Publication Date: 2020-09-18
    Description: This paper analyzes the digital modelling of radiance reflectance of the sea surface when the water column is polluted by oil-in-water emulsion. A method tracking the fate of two billion virtual solar photons was applied to obtain the angular distribution of bottom-up radiance for a plane of sunlight striking the sea surface. For the calculations, the inherent optical properties of seawater characteristic for the Gulf of Gdańsk (southern Baltic Sea) were used. The analyses were performed for two types of oils with extremely different optical properties for an oil concentration of 10 ppm and for a roughened sea surface with a wind speed of 2 m/s. The spectral index for oil detection in seawater for different viewing angles was determined based on the results obtained for reflectance at eight wavelengths in the range of 412–676 nm for viewing angle in the range from 80° to 0°, both on the side of incidence of direct sunlight and on the opposite side. The resulting calculated spectral indexes for different wavelength combinations indicated significant dependence on the viewing angle.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 3
    Publication Date: 2017-06-02
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 4
    Publication Date: 2019-08-31
    Description: This study analyzed the fluorometric laboratory tests for the detection of the presence of oil in seawater in cases corresponding to the real situation in the sea: when the point of seawater sampling is not in the same place as the appropriate sensor. The phenomenon of fluorescence exhibited by both natural and alien substances (oil) in the sea was used. The possibility of oil detection in the water column based on a fluorometric index (FI) extracted from the excitation–emission matrix (EEM) was studied. Laboratory tests were carried out on water taken from the Gulf of Gdańsk (Baltic Sea). Seawater samples were contaminated with small amounts of various types of oil (the lowest oil-to-water ratio was 0.5 × 10−6). A statistically significant difference was found between FI values for uncontaminated seawater and seawater exposed to various kinds of oil (i.e., crude oils, lubricant oils, and fuels).
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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  • 5
    Publication Date: 2020-02-06
    Description: This paper presents a model of upwelling radiation above the seawater surface in the event of a threat of dispersed oil. The Monte Carlo method was used to simulate a large number of solar photons in the water, eventually obtaining values of remote sensing reflectance (Rrs). Analyses were performed for the optical properties of seawater characteristic for the Gulf of Gdańsk (southern Baltic Sea). The case of seawater contaminated by dispersed oil at a concentration of 10 ppm was also discussed for different wind speeds. Two types of oils with extremely different optical properties (refraction and absorption coefficients) were taken into account for consideration. The optical properties (absorption and scattering coefficients and angular light scattering distribution) of the oil-in-water dispersion system were determined using the Mie theory. The spectral index for oil detection in seawater for different wind conditions was determined based on the results obtained for reflectance at selected wavelengths in the range 412–676 nm. The determined spectral index for seawater free of oil achieves higher values for seawater contaminated by oil. The analysis of the values of the spectral indices calculated for 28 combinations of wavelengths was used to identify the most universal spectral index of Rrs for 555 nm/440 nm for dispersed oil detection using any optical parameters.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
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