ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, [(S)-2-(anilinomethyl)pyrrolidine-N,N′]-chloro(η6-para-cymene)ruthenium(II) chloride, [RuCl-(C10H14)(C11H16N2)]Cl, has been synthesized by the reaction of [RuCl2(p-cymene)]2 (p-cymene is para-isopropyltoluene) with (S)-2-(anilinomethyl)pyrrolidine in triethylamine/2-propanol. The Ru atom is in a pseudo-tetrahedral environment coordinated by a chloride ligand, the aromatic hydrocarbon is linked in a η6 manner and the amine is linked via its two N atoms. The chloride anion is involved in hydrogen bonding with the diamine moieties through N—H...Cl interactions, with N...Cl distances of 3.273 (4) and 3.352 (4) Å.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100008787
Permalink