ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The cation of the title compound, [Au4(PPh2CH2PPhCH2PPh2)2Cl2][Au(C6F5)3Cl]2 or [Au4Cl2(C32H29P3)2][AuCl(C6F5)3]2, displays a rhomboidal geometry for the Au atoms, with short Au...Au distances of 3.104 (2) and 3.185 (1) Å; the linear coordination at the AuI atoms is distorted: P—Au—P 164.7 (2)° and P—Au—Cl 170.67 (11)°. The anion shows the expected square-planar geometry at AuIII, with the Au atom 0.022 (5) Å out of the plane of the four donor atoms.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100012518
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