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  • 1
    Electronic Resource
    Electronic Resource
    On the PVC chlorination mechanism (1981)
    Springer
    Polymer bulletin 5 (1981), S. 167-174 
    Details
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A radiochemical method was used to study PVC chlorination. A reaction mechanism was proposed based on the results obtained from chlorination of 36chlorine labeled PVC. A mechanism was proposed also for chain transfer reaction to polymer in vinyl chloride polymerization.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00265161
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    The chain transfer to polymer in vinyl chloride bulk polymerization (1982)
    Springer
    Polymer bulletin 6 (1982), S. 463-469 
    Details
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Self grafting of PVC has been studied by introducing a 36-chlorine labelled low molecular PVC fraction in the polymerization mixture of vinyl chloride. The fractionation of the polymer obtained follows the same pattern as a synthetic mixture of the polymer with the same fraction. It is concluded that, under those working conditions, chain transfer to the polymer with grafting has not taken place, at least in a considerable extent.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00255807
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  • 3
    Electronic Resource
    Electronic Resource
    On the mechanism of isocyanate preparation by the phosgenation reaction (1981)
    Springer
    Reaction kinetics and catalysis letters 18 (1981), S. 427-430 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Механизм превращения гидрохлоридов амина в изоцианаты в процессе фосгенирования был подтвержден с помощью радиоизотопного обмена между дигидрохлоридом (36Cl) п,п'-диамино-1,2-дифенилэтана и фосгеном. Реакция протекает через переходный комплекс гидрохлорида амина с фосгеном, образующегося на поверхности гидрохлоридных кристаллов.
    Notes: Abstract A new mechanism of the transformation of amine hydrochlorides into isocyanates during the phosgenation process was proposed on the basis of radioisotope exchange between p,p'-diamino-1,2-diphenylethane dihydrochloride (36Cl) and phosgene. The reaction proceeds through a transition complex of amine hydrochloride and phosgene, formed on the surface of the hydrochloride crystals.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02065636
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  • 4
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    On the PVC chlorination mechanism (1981)
    Springer
    Details
    Publication Date: 1981-01-01
    Print ISSN: 0170-0839
    Electronic ISSN: 1436-2449
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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