ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 53 (2002), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The soils and sediments of the uplands in the Manaus region are described and analysed along a representative cross-section. There are two broad types of features, lateritic and redoximorphic. Their formation is linked to two main processes acting under contrasted hydrological regimes. The first process, acting under well-drained conditions, is lateritization. It has transformed strongly weathered sediment into soil and led to depletion of silica (mainly quartz) as well as to relative accumulation of both kaolinite and iron oxides (haematite and goethite). Crystallographic changes observed in the latter have resulted from alternating dissolution and crystallization cycles without significant transfer of iron and alumina. However, in the uppermost soil, dissolution of kaolinite has prevailed over crystallization, leading to depletion of clay and the formation of tiny crystals of gibbsite disseminated throughout the groundmass. The second process results from the development of reducing conditions in groundwater giving redoximorphic features in lateritic soils and sediments. In the sediments, iron has been depleted by regional aquifers to form a pallid zone. In the soil, large amounts of iron and minor amounts of alumina, mainly from aluminous goethite, have been mobilized at first in small patches, which with further mobilization and vertical transfer of these elements have increased in size and have led to the formation of bleached horizons over thin iron pans. Iron has crystallized predominantly as haematite in the iron pans and alumina as large crystals of gibbsite in soil voids. Formation of impervious iron pans holds up fluctuating perched groundwater in the overlying horizons depending on rainfall events.Neotectonic events (formation of uplifted blocks and small grabens) have markedly altered the hydrological regimes. In the uplifted blocks, the soil has been deeply truncated and iron loss has been checked in the uppermost sediment. By contrast, mobilization of iron has been initiated at various places in the soil of the small grabens. In this way tectonic events have checked mobilization of iron in sediments but activated it in soils, leaving spectacular fingerprints on the landscape.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The red and yellow colours of ferralitic soils in the tropics have for long intrigued pedologists. We have investigated the upward yellowing in a 10-m thick profile representative of the Ferralsols of the plateaux of the Manaus region of Brazil. We determined changes in the nature and crystal chemistry of their Fe oxides by optical and Mössbauer spectroscopy as well as Rietveld refinement of X-ray diffraction patterns. We attribute the upward yellowing of the soil to a progressive transformation of the Fe oxides at nearly invariant iron contents. Aluminium in contrast is strongly mobilized in the uppermost clay-depleted topsoil where there is preferential dissolution of kaolinite and crystallization of gibbsite. Haematite decreases from 35 to 10% of the Fe oxides from the bottom to the top of the profile and the particles become smaller (75–10 nm). Its Al for Fe-substitution remains almost unchanged (10–15 mol %). The average Al-substitution rate of goethite increases from 25 to 33 mol %, and its mean crystal diameter remains in the range 20–40 nm. The proportion of Al-rich goethite (33 mol %) increases at the expense of less Al-substituted Fe oxides (haematite and goethite). This conversion with restricted transfer of iron means that the amount of Al stored in Fe oxides gradually increases. Kaolinite, haematite and Al-poor goethite are thus witnesses of earlier stages of ferralitization of the soil. In contrast, Al-rich goethite and gibbsite initiate the alitization (or bauxitization) of the soil. They correspond to the last generation of soil minerals, which most likely reflects the present-day weathering conditions. The progressive replacement of kaolinite, haematite and Al-poor goethite by new generations of Al-rich goethite and gibbsite attests to greater activities of water and aluminium and smaller activity of aqueous silica in the topsoil than in the subsoil. We interpret this as a consequence of longer periods of wetting in the topsoil that could result from soil aging, more humid climate or both.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 26 (1999), S. 530-538 
    ISSN: 1432-2021
    Keywords: Key words57Fe Mössbauer ; Tektite glasses ; Distribu-tion of hyperfine parameters
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract Tektite glasses are investigated using 57Fe Mössbauer spectroscopy. Room temperature spectra analysis is performed using two complementary analytical methods based on two-dimensional distributions of both isomer shift and quadrupole splitting. No a priori correlation between the two hyperfine parameters is considered. The first method, based on a shape independent distribution, provides the justification for the Gaussian distribution shape used in the second method. No ferric iron contribution is evidenced by Mössbauer spectra analysis in these samples, although several criteria are used. Ferrous iron sites are shown to be continuously distributed between four- and five-fold co-ordinated sites.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 1998-08-01
    Description: Iron bands, fragipans and duripans are common in yellow low-activity clay soils developed from the Barreiras Group in coastal plateaus of northeastern Brazil. Such indurated horizons are found in depressions of the plateaus where sugar cane growth is greatly reduced. Little research has being done on the nature of their bonding agents and their genesis. Research carried out in arid zones has frequently attributed duripan consistency to amorphous silica; however, duripans in northeast Brazil occur under higher rainfall (1500–2000 mm). The objective of this work was to study the nature and distribution of soil features in a plateau to better understand the processes associated with soil hardening. Two transects, across a small and a large depression, were investigated using field soil characterisation, micromorphological techniques, and mineralogical and geochemical analyses.The formation of the indurated horizons studied is due to two sequential processes: development of aquic conditions and incipient podzolization. Such processes have affected the upper part of a thin (0.6 m in large depressions) compact clay horizon, showing horizontal plans likely inherited from the sediment. Onset of aquatic conditions formed the first fragipans overlying iron bands. Later, aquic conditions are combined with incipient podzolization to produce bleached loose horizons overlying duripans and iron bands. As the bonding agents in the duripans are organo-metallic complexes, these duripans appear to be very different from those described in arid environments. Key words: Low activity clay Ultisols, Barreiras Group, iron bands, fragipans and duripans, organo-metallic complexes
    Print ISSN: 0008-4271
    Electronic ISSN: 1918-1841
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2017-07-13
    Print ISSN: 0031-9007
    Electronic ISSN: 1079-7114
    Topics: Physics
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
  • 7
    Publication Date: 2014-04-03
    Description: Hydroxyl defects in pure forsterite are usually ascribed to incorporation of protons fully compensating the electrostatic charge of cationic vacancies. However, partially compensated vacancies have been predicted from theoretical considerations. Here, we theoretically determine the structural, vibrational and infrared spectroscopic properties of partially protonated cationic vacancies in forsterite using a first-principles theoretical modeling approach. The results show that the partial protonation of Si vacancies strongly modifies their spectroscopic properties with respect to those of the fully protonated (4H) x Si defect, leading to a significant downshift of at least one of the OH-stretching absorption bands. Comparison with experimental observations shows that such defects are unlikely to significantly contribute to the speciation of OH groups in pure synthetic forsterite samples. A partial protonation of Mg vacancies has a weak effect on the spectroscopic properties of OH groups, compared with those of the fully protonated defect, making it difficult to assess their occurrence from spectroscopic observations only.
    Print ISSN: 0935-1221
    Electronic ISSN: 1617-4011
    Topics: Geosciences
    Published by Schweizerbart
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2014-10-02
    Description: Experimental and theoretical evidence for the coupled substitution of B and H in synthetic forsterite and a natural olivine is presented. The intensities of OH bands at 3704 cm –1 (//z), 3598 cm –1 (//x,y), and 3525 cm –1 (//x) in a heterogeneous B-doped synthetic forsterite crystal matches the zoning of B concentration measured by ion probe. The two anti-symmetric stretching vibrations of BO 3 groups occur at 1301 cm –1 (//x) and 1207 cm –1 (//z) for the 10 B and at 1256 and 1168 cm –1 for the 11 B isotope. A microscopic model of the mixed (B,H) defect that accounts for experimental observations is obtained from quantum mechanical calculations. The BO 3 group lies on the (O3-O1-O3) face of the vacant Si site and the H atom is bonded to the O2 atom at the remaining apex. The occurrence of the same OH bands associated with 3 BO 3 vibrations in a natural olivine sample from Pakistan confirms the occurrence of this defect in nature. The three diagnostic OH bands can be used as a signature of H associated with boron substitution in olivine and forsterite, leading to a quantitative analysis of their contribution to H-defects.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2019
    Description: 〈span〉The attenuated total reflectance (ATR) spectra of two calcite samples have been measured using Ge and diamond internal reflection elements. One of the samples was obtained by precipitation from solution and displays sub-micrometer sized particles. The second sample was obtained by grinding a single-crystal of calcite (“Iceland spar” variety). Theoretical spectra were obtained by computing the reflection coefficient of the interface between the ATR internal reflection element and a homogeneous effective medium representing the powder sample. The dielectric properties of the effective medium have been determined from those of bulk calcite using the Bruggeman approach which is adequate for standard powders with intermediate fractions of solid and empty porosity. Although this modeling approach provides a quantitative interpretation of the broadening of strong absorption bands in the calcite ATR spectra, it fails to reproduce the apparent splitting of the strong ν〈sub〉3〈/sub〉 CO〈sub〉3〈/sub〉 band. This problem was solved by combining the electrostatic modeling approach with a semi-quantum model of the dielectric tensor of bulk calcite, which allows for a frequency-dependent damping of the ν〈sub〉3〈/sub〉 CO〈sub〉3〈/sub〉 excitation. The frequency-dependence is ascribed to a multiphonon-related resonance in the ν〈sub〉3〈/sub〉 CO〈sub〉3〈/sub〉 phonon self-energy at a frequency close to its transverse optical frequency. The combination of approaches exposed in the present study makes it possible to discriminate among physically different processes affecting the powder infrared spectra of calcite, some being related to the long-range nature of electrostatic interactions in polar materials and others being related to atomic-scale anharmonic interactions between vibrational modes.〈/span〉
    Print ISSN: 0935-1221
    Electronic ISSN: 1617-4011
    Topics: Geosciences
    Published by Schweizerbart
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2013-05-11
    Description: We propose a microscopic model of the dominant carbonate for phosphate substitution in fluorapatite. A well-crystallized sedimentary fluorapatite sample containing ~2.3 ± 0.8 wt% of carbonate was investigated using Fourier transform infrared spectroscopy (FTIR) and 13 C and 19 F magic angle spinning nuclear magnetic resonance (MAS NMR). About 75% of the carbonate groups replace the phosphate group ("B-site"), whereas a lesser contribution from carbonate groups located in the structural channels ("A-site") is observed. Beside the dominant 19 F NMR signal of channel ions at ~ –102 ppm, an additional signal corresponding to ~8% of fluoride ions is observed at –88 ppm. 19 F double quantum-single quantum (DQ-SQ) MAS NMR and 13 C{ 19 F} frequency-selective Rotational Echo DOuble Resonance (REDOR) experiments prove that this additional signal corresponds to isolated fluoride ions in the apatite structure, located in close proximity of substituted carbonate groups. Density functional theory (DFT) calculations allow us to propose a composite carbonate-fluoride tetrahedron defect model accounting for these experimental observations. The planar carbonate ion lies in the sloping face of the tetrahedron opposite a fluoride ion occupying the remaining vertex, together replacing the tetrahedral phosphate ion. This "francolite-type" defect leads to a diagnostic narrow IR absorption band at 864 cm –1 that could be used as a guide to, e.g., detect the incipient transformation of fossil bone and teeth samples.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...