ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Solvophobic and polarity parameters are used to explain the endo/exo selectivity of the reaction between cyclopentadiene and methyl acrylate. A good linear regression model with Sp and ETN is obtained. The existence of an intrinsic correlation between the Sp and ETN values, which makes the interpretation of the results difficult, is shown. A comparison of the results with other previously reported showed that the relative influence of Sp and ETN on selectivity depends on the nature of the reagents.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610040108
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