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  • 1
    Electronic Resource
    Electronic Resource
    Anionic polymerization of star-shaped nylon 6 with a trifunctional initiator (1989)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3637-3649 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The anionic polymerization of ∊-caprolactam (CLM) has been shown to proceed at high reaction rate when catalyzed by metallic lactamates and initiated by acyllactams. The role of initiator and catalyst concentration on the process of ∊-caprolactam anionic polymerization has been explored, with the aim of selecting the most suitable experimental conditions for reaction injection molding (RIM). The overall polymerization rates and physical properties for reaction injection molding of star-shaped nylon 6 homopolymer have been studied by the quasi-adiabatic process. In order to model the actual rapid molding conditions, time vs. temperature reaction profiles were measured, and the relative rates of polymerization subsequently determined from these data.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1989.080271107
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  • 2
    Electronic Resource
    Electronic Resource
    Nylon 6/polyisocyanurate interpenetrating polymer networks (IPNs) (1989)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3619-3635 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two component interpenetrating networks (IPNs) of the SIN type (simultaneous interpenetrating networks), composed of a polyisocyanurate network and a star-shaped nylon 6, were made. The overall polymerization rates and physical properties for reaction injection molding (RIM) have been studied by the quasi-adiabatic process. In order to model the actual rapid molding conditions, time versus temperature reaction profiles were measured, and the relative rates of polymerization subsequently determined from these data.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1989.080271106
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    Paper (German National Licenses)
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