ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Stable diazo compounds of the azafluorene series, viz., 9-diazo-4-azafluorenone and 1,3-diphenyl-4-azafluorene, were obtained from 4-azafluorenone and 1,3-diphenyl-4-azafluorene tosylhydrazones. 1′,2′-Dicarbomethoxyspiro(4-azafluorene-9,3′-cyclopropane) was obtained from 4-azafluorenone tosylhydrazone, and 4′,5′-dicarbomethoxyspiro(4-azafluorene-9,3′-pyrazolenine) was obtained from 9-diazo-4-azafluorene. It is assumed that the product in the latter case is obtained as a result of reaction of a carbene, viz., 4-azafluorenylidene carbene, which is formed from 9-diazo-4-fluorene, with dimethyl acetylenedicarboxylate.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00473562
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