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  • 1
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 45 (1989), S. 124-128 
    ISSN: 1600-5740
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Chemistry of heterocyclic compounds 10 (1974), S. 1241-1245 
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The conversion of piperazine under pulse-chromatographic conditions on catalysts — anhydrides of polyvalent acids and metal oxides of variable valence (P2O5, Cr2O3, MoO3, WO3, CuO, CoO, NiO, MoO3 + P2O5 andWO3 + B2O3 + CoO) —applied on Chromsorb W was investigated. The principal reaction direction in all cases is dehydrogenation of piperazine to pyrazine (90–94% yields). The most selective catalyst is CuO. The dehydrogenation is accompanied by slight hydrogenolysis to give ethylamine, diethylamine, methylpyrazine, and N-ethylpiperazine. The conversion of piperazine to P2O5 is characterized by the lowest activation energy on metal oxides.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Chemistry of heterocyclic compounds 30 (1994), S. 822-828 
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The reactions of 1,2-diaminopropane, 1-amino-2-propanol, 1-amino-2-ethanol and N-(β-aminoethyl)-1,2-diaminoethane in the gas phase over copper chromite have been investigated with the objective of synthesising nitrogen containing heterocycles. At 240–360°C 1,2-diaminopropane gave principally methyl- and 2,5-dimethylpyrazine, whereas the basic reaction for 1-amino-2-propanol was dehydration to give 1-aminoethyl-2-methylaziridine (with a selectivity of up to 78%). The main cyclic product from the dehydration of 1-amino-2-ethanol was pyrazine, while piperazine was farmed together with pyrazine from N-(β-amonoethyl)-1-2-diaminoethane.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Chemistry of heterocyclic compounds 29 (1993), S. 1134-1141 
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The contact conversion of 1,2-diaminoethane over a tungsten trioxide catalyst at 240–580°C has been studied by an impulse chromatographic method. The basic reaction path under these conditions is unimolecular deaminocyclization to give aziridine (31–35%). Piperazine and triethylenediamine, products of bi- and trimolecular deaminocyclization, are present as products. The deamination process is accompanied by coupled dehydrogenation and hydrogenolysis reactions. Addition of the acid anhydrides SiO2, P2O5 and B2O3 to the catalyst increases its activity but has only a negligible affect on the activation energy of the process.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Chemistry of heterocyclic compounds 34 (1998), S. 1406-1408 
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The conversions of furan, di- and tetrahydrofuran, and di- and tetrahydropyran on a molybdenum catalyst in a hydrogen atmosphere have been investigated. The studied cyclic systems readily undergo mutual conversions at 125–215°C and also undergo a hydrogenation-dehydrogenation reaction. Expansion of the unsubstituted furan rings to pyran without the introduction into the reaction medium of components capable of generating methyl radicals are described by us for the first time.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Chemistry of heterocyclic compounds 19 (1983), S. 1249-1262 
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The process of the catalytic synthesis of a number of nitrogenous heterocyclic compounds based on the utilization of reactions involving the amination of oxygen-containing heterocycles, the dehydration cyclization of amino alcohols, the deamination of di- and polyamines, and the intermolecular dehydration cyclization of glycols with diamines have been considered.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Chemistry of heterocyclic compounds 18 (1982), S. 740-745 
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The transformations of 1,3-diaminopropane and 3-amino-1-propanol under pulse conditions over tungsten trioxide in an inert atmosphere at 300–500 °C were investigated. The transformation of 1,3-diaminopropane leads to the formation of saturated pyrimidine bases; the maximum selectivity of the formation of hexahydropyrimidine bases at 300 °C is 60%, while the selectivity of the formation of tetrahydropyrimidine bases is 20% (400 °C). In the case of 3-amino-1-propanol the overall yield of heterocyclic bases was less than 5%, and piperazine and pyrazine derivatives were observed as the cyclic products; the formation of pyrimidine bases was not observed.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Chemistry of heterocyclic compounds 3 (1967), S. 271-286 
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A study is made of the deamination of diethylenetriamine over acidalkali catalysts, i. e., kaolin and alumina with promoters. Promoters which raise the acidity of the catalyst, affect the formation of triethylene diamine favorably. Increasing the amount of additive increases the amount of triethylenediamine, and cuts the optimum temperature at which it is formed. On kaolin or Al2O3+15% B2O3, the yield of triethylenediamine amounts to 30% theory. Addition of MoO3 facilitates dehydrodeamination and hydrogenolysis of the diethylenetriamine. The optimum promoter for preparing pyrazine is MoO3 along with a small amount of acid oxides. On the Al2O3+5% MoO3+1% P2O5, the pyrazine yield is 27.5% theory. Triethylenediamine can be separated from mixtures of it with piperazine by azeotropic distillation with mxylene or a mixture of mesitylene and α-memylnaphthalene.
    Type of Medium: Electronic Resource
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  • 9
    Publication Date: 2015-09-01
    Print ISSN: 1070-664X
    Electronic ISSN: 1089-7674
    Topics: Physics
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  • 10
    Publication Date: 2015-10-07
    Description: This study evaluates the relative impact of snow-surface coupling, long-wave radiation, and turbulent mixing on the development of the stable boundary layer over snow. Observations at three sites are compared to WRF single-column model (SCM) simulations. All three sites have snow-covered surfaces but are otherwise contrasting: Cabauw (Netherlands, grass), Sodankylä (Finland, needle-leaf forest) and Halley (Antarctica, ice shelf). All cases are characterized by stable, clear-sky, and calm conditions. Part 1 of this study determined the optimal SCM forcing strategy. In this study, the process intensities from that reference are perturbed to study their relative significance and to assess which process could be responsible for the most optimal agreement between model and observation. The analysis reveals a large variability in the modelled atmospheric state and surface parameters. Overall, the modelled gradients of temperature and moisture are under-estimated but decreasing the process intensities improves this. The impact is strongest with reduced mixing, though this then causes the model to overestimate the near-surface wind speed. To study the surface energy balance terms, we use so-called ‘process diagrams’. The achieved variation between the sensitivity runs indicates the model sensitivity to each process. The overall sensitivity is similar for the three sites but the relative offsets in the position of the sensitivity runs with respect to the observations differ, hampering general recommendations for model improvement. Furthermore, sometimes a meaningful interpretation of observations is troublesome, which hampers the comparison with model results. Radiation is relatively more important at Cabauw and Sodankylä, whilst coupling plays a more important role at Halley. The sensitivity analysis is performed with two boundary-layer schemes (MYJ, YSU). YSU generates larger, more accurate gradients of atmospheric temperature and humidity, while wind speeds are predicted better with MYJ. The behaviour of an increase in 2 m temperature with decreased mixing is most obvious with YSU.
    Print ISSN: 0035-9009
    Electronic ISSN: 1477-870X
    Topics: Geography , Physics
    Published by Wiley
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