Publication Date:
2018-09-08
Description:
Materials, Vol. 11, Pages 1652: Enhancement in Curie Temperature of Yttrium Iron Garnet by Doping with Neodymium Materials doi: 10.3390/ma11091652 Authors: Esperanza Baños-López Félix Sánchez-De Jesús Claudia A. Cortés-Escobedo Arturo Barba-Pingarrón Ana María Bolarín-Miró The effect of the substitution of Y3+ by Nd3+ on the structural and magnetic properties of neodymium-doped yttrium iron garnet, NdxY3−xFe5O12 with x in the range of 0–2.5, is presented. Oxide powders of Fe2O3, Nd2O3, and Y2O3 were mixed in a stoichiometric ratio and milled for 5 h using high-energy ball milling, before being uniaxially pressed at 900 MPa and annealed at 1373 K for 2 h to obtain NdxY3−xFe5O12 (0 ≤ x ≤ 2.5). It was found that the mechanical milling of oxides followed by annealing promotes the complete structural formation of the garnet structure. Additionally, the X-ray diffraction patterns confirm the complete introduction of Nd3+ into the garnet structure with a neodymium doping concentration (x) of 0–2.0, which causes a consistent increment in the lattice parameters with the Nd3+ content. When x is higher than 2.0, the yttrium orthoferrite is the predominant phase. Besides, the magnetic results reveal an increase in the Curie temperature (583 K) as the amount of Nd3+ increases, while there was enhanced saturation magnetization as well as modified remanence and coercivity with respect to non-doped YIG.
Electronic ISSN:
1996-1944
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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