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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 65-81 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Copolymers of caprolactam with caprylolactam and laurolactam were prepared by activated anionic copolymerization under adiabatic conditions, at an initial polymerization temperature of T0 = 130°C. The drop of the crystalline phase content and changes of the copolymer morphological structure depending on the content of comonomers result in increasing toughness and deformability due to enhanced yielding ability. The dependences of the copolymer structure and properties on the concentration of comonomers are different for the two series of copolymers. This results from different courses of the polymerization and crystallization history as a consequence of a large difference between polymerization rates of caprylolactam and laurolactam.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 1387-1401 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Crosslinked polyamides prepared by copolymerization of ∊-caprolactam with bislactams under conditions of activated anionic polymerization proceeding adiabatically below their melting point show differences in physico-mechanical properties. Owing to varying copolymerization rates of bislactams, depending on the position of the connecting bridge of the bislactam in relation to the amido group, copolymers with different morphological structure are formed. The differences in the mechanical properties of the copolymers are explained on the basis of the differences in the morphological structure. This explanation is supported by results obtained by measuring the thermal and dynamic properties.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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