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  • 1
    Publication Date: 2023-02-24
    Keywords: Barium; CAA_Coppermine; Calcium; Canadian Arctic Archipelago; Carbon, organic, dissolved; Chloride; Comment; DATE/TIME; Geochemistry; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; inorganic carbon; Magnesium; major ions; Potassium; River; rivers; Sodium; Strontium; Sulfate; water isotopes; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 371 data points
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  • 2
    Publication Date: 2023-02-24
    Keywords: Barium; CAA_Freshwater_Creek; Calcium; Canadian Arctic Archipelago; Carbon, organic, dissolved; Chloride; Comment; DATE/TIME; Geochemistry; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; inorganic carbon; Magnesium; major ions; Potassium; River; rivers; Sodium; Strontium; Sulfate; water isotopes; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 280 data points
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  • 3
    Publication Date: 2023-02-24
    Keywords: Alkalinity, total; Barium; CAA_Akpat_Kuunga; CAA_Burnside_River; CAA_Charles_York_River; CAA_Coppermine; CAA_Creswell_River; CAA_Cunningham_River; CAA_Devon_Island; CAA_Ehoktok_Lake; CAA_Ekalluk_River; CAA_Ekalulia_Lake_out; CAA_Ellice_River; CAA_Elu_Inlet; CAA_Ferguson_Lake; CAA_Freshwater_Creek; CAA_Garnier_River; CAA_Glacier_River; CAA_Greiner_LS_Greiner_Lake_in; CAA_Greiner_LS_Greiner_Lake_out; CAA_Greiner_LS_Long_Lake_at_Mount_Pelly; CAA_Greiner_LS_Second_Lake; CAA_Greiner_LS_Upper_Long_Lake; CAA_Halokvik_River; CAA_Jayko_River; CAA_Koignuk_River; CAA_Lake_in_Upper_Tree_River; CAA_Le_Feuvre_Inlet; CAA_Marcil_Creek; CAA_Mecham_River; CAA_Pasley_River; CAA_Rain_Cambridge_Bay_NU; CAA_Rain_Kugluktuk_NU; CAA_Saaqu_River; CAA_Simpson_River; CAA_Small_Lake_North_of_Ehoktok_Lake; CAA_Tingmeak_River; CAA_Tree_River; CAA_Wentzel_Lake; CAA_Western_River; Calcium; Canadian Arctic Archipelago; Carbon, inorganic, dissolved; Carbon, organic, dissolved; Chloride; Comment; DATE/TIME; Event label; Geochemistry; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; inorganic carbon; LATITUDE; LONGITUDE; Magnesium; major ions; Potassium; River; rivers; Salinity; Sodium; Station label; Strontium; Sulfate; water isotopes; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 634 data points
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  • 4
    Publication Date: 2024-06-25
    Description: This data set describes geochemical samples collected from 25 rivers and 11 lakes throughout the Canadian Arctic Archipelago (CAA). CAA rivers were sampled as part of the Canadian Arctic Archipelago Rivers Program (CAA-RP) and the Canadian Arctic GEOTRACES program with access via land, water, and air during the summer seasons of August 1-September 9, 2014, and August 11-19, 2015. Time series observations were also collected from the Coppermine River in Kugluktuk, Nunavut (NU) (year-round; August 5, 2014 to August 23, 2016), and from Freshwater Creek in Cambridge Bay, NU (open water only; June 19, 2014 to September 16, 2016). Lake samples were collected opportunistically during float plane air-surveys in 2014 and 2015 as part of the CAA-RP study in the southern CAA. Precipitation was collected during two significant rain events in Kugluktuk, NU (August 25, 2015) and Cambridge Bay, NU (August 20, 2016). River water samples were collected according to methods developed by the Arctic Great Rivers Observatory (Arctic-GRO; http://www.arcticgreatrivers.org/); lake sampling followed the same general methods, with collection carried out in deeper waters away from the shore; rain samples were collected using an HCl cleaned plastic box and processed immediately the morning following the rain event in order to limit the influences of evaporation. Sampling and analytical methods are described in detail in Brown et al., 2020. This data set includes the raw data supplied in Supplementary Tables S2 (Geochemical Data for the CAA-Rivers Project, collected from 2014 - 2016) and S3 (Geochemical Time Series Data for the Coppermine River and Freshwater Creek collected from 2014 - 2016) that accompany Brown et al., 2020. In addition to geochemical observations, the following calculated parameters can be found in Supplementary Table S2 of Brown et al., 2020: drainage basin area; predominant bedrock lithology; percent coverage of lakes; and surficial geology characteristics. These parameters were determined for each river drainage basin as described in the text and associated references found in Brown et al., 2020.
    Keywords: Canadian Arctic Archipelago; Geochemistry; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; inorganic carbon; major ions; rivers; water isotopes
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 5
    Publication Date: 2024-05-04
    Description: This dataset contains methane and nitrous oxide dissolved gas concentration, dissolved methane carbon isotope, and ancillary hydrographic data from research cruises in the North American Arctic Ocean between 2015-2018. It also contains methane and nitrous oxide dissolved gas concentration and dissolved methane carbon isotope data from rivers in the Canadian Arctic Archipelago region collected between 2017-2019.
    Keywords: Arctic; ArcticNet; GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; International Polar Year (2007-2008); IPY; Marine Biogeochemistry and Surface Exchange of Climate Active Gases; Methane; nitrous oxide; ocean; rivers
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 6
    Publication Date: 2024-06-25
    Description: This dataset contains methane and nitrous oxide dissolved gas concentration and dissolved methane carbon isotope data from rivers in the Canadian Arctic Archipelago region collected between 2017-2019. River samples were collected during CCGS Amundsen cruises using a helicopter to travel to the rivers. At each river site, river water was pumped through tubing using a peristaltic pump. Water was collected into glass serum bottles and allowed to overflow three times before preserving with mercuric chloride and sealing with butyl rubber stoppers and aluminum crimp seals. Gas concentrations were determined using a purge and trap system coupled to a gas chromatograph/mass spectrometer, following the method of Capelle et al. (2015). For methane 𝛿13C, samples (one sample per event) were pre-concentrated through a purge and trap system (Finnigan PreCon Trace Gas Pre-Concentrator) and measured with a Finnigan Delta XP Plus mass spectrometer following the method of Damm et al. (2015).
    Keywords: AMD17_2; AMD17_2_CMBB-1; AMD17_2_CMCMG-1; AMD17_2_CMCR-1; AMD17_2_CMCR2-1; AMD17_2_CMGR-1; AMD17_2_CMLFI-1; AMD17_2_CMMB-1; AMD17_2_CMMR-1; AMD18_3; AMD18_3_CMCR-1; AMD18_3_CMER-1; AMD18_3_CMGR-1; AMD18_3_CMLFI-1; AMD18_3_CMSR-1; AMD18_3_CMSR2-1; AMD18_3_CMTR-1; AMD19_2; AMD19_2_RI135-1; AMD19_2_RI6.1-1; AMD19_2_RICP-1; AMD19_2_RIDIE-1; AMD19_2_RIDIW-1; AMD19_2_RIDIW-N-1; AMD19_2_RIEE-1; AMD19_2_RIESC-1; AMD19_2_RIHI-1; AMD19_2_RISG-1; AN1702; AN1902; Arctic; ArcticNet; CAA; Calculated; Canadian Arctic Archipelago; CCGS Amundsen; CMBB; CMCMG; CMCR; CMCR2; CMER; CMGR; CMLFI; CMMB; CMMR; CMSR; CMSR2; CMTR; Conductivity, electrical; DATE/TIME; Event label; Gas chromatography - Mass spectrometry (GC-MS); GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; International Polar Year (2007-2008); IPY; LATITUDE; Location; LONGITUDE; Marine Biogeochemistry and Surface Exchange of Climate Active Gases; Methane; Methane, dissolved; Methane, standard deviation; nitrous oxide; Nitrous oxide, dissolved; Nitrous oxide, standard deviation; Oakton Con5; ocean; PUMP; RI135; RI6.1; RICP; RIDIE; RIDIW; RIDIW-N; RIEE; RIESC; RIHI; RISG; River; rivers; Station label; Temperature, water; Thermo Trace GC coupled to ThermoFinnigan DELTAplus XP (GC-C-IRMS); Water pump; δ13C, methane, dissolved
    Type: Dataset
    Format: text/tab-separated-values, 230 data points
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  • 7
    Publication Date: 2024-06-25
    Description: This data set describes the stable water isotope (δ18O-H2O, δ2H-H2O), Dissolved Organic Carbon (DOC), and Nutrient (Nitrate + Nitrite, Phosphate, Silicate) data collected from 53 rivers, lakes, and glaciers throughout the Canadian Arctic Archipelago (CAA) and Hudson Bay as part of the Canadian Arctic Archipelago Rivers Program (CAA-RP; 2016 – 2019); ArcticNet / Amundsen Science biogeochemical surveys (2017-2019); the Canada 150 C3 Expedition (2017); and the BaySys project (2018). Water samples were collected according to methods developed by the Arctic Great Rivers Observatory (http://www.arcticgreatrivers.org/), described in detail in Brown et al., 2020. Water collected for stable water isotope, DOC, and Nutrient analyses was filtered through 0.22 μm Sterivex cartridges (Millipore) into triply rinsed glass (isotopes) or HDPE (Nutrients, DOC) vials; HDPE vials were acid cleaned prior to use. Samples for the determination of DOC and Nutrients were frozen until analyses, whereas stable isotope samples were stored in the dark at room temperature or refrigerated until analyses. Analytical methods are described in the accompanying metadata file. Where indicated, water Temperature and Conductivity at the time of sampling were determined as described in the dataset metadata file.
    Keywords: AMD-2017-01; AMD-2017-02; AMD-2017-03; AMD-2017-04; AMD-2017-05; AMD-2017-06; AMD-2017-07; AMD-2017-08; AMD-2019-01; AMD-2019-02; AMD-2019-03; AMD-2019-04; AMD-2019-05; AMD-2019-06; AMD-2019-07; AMD-2019-08; AMD-2019-09; AMD-2019-10; AMD-2019-11; AN-1801-01; AN-1801-02; AN-1801-03; AN-1801-04; AN-1801-05; AN-1801-06; AN-1803-01; AN-1803-02; AN-1803-03; AN-1803-04; AN-1803-05; AN-1803-06; AN-1803-07; BAY-2016-21-02; BR-2016-21-03; BR-2016-21-04; BUR-2017; C3-2017-01; C3-2017-02; C3-2017-03; C3-2017-04; C3-2017-05; C3-2017-06; C3-2017-07; C3-2017-08; C3-2017-09; C3-2017-10; CAA; CAA-RP; Canadian Arctic Archipelago; Carbon, organic, dissolved; Conductivity, electrical; DATE/TIME; Date/Time local; DEPTH, water; Event label; Geochemistry; GW-2016-21-01; Identification; Laboratory number; LATITUDE; LONGITUDE; Nitrate and Nitrite; Phosphate; QU-2017-01; QU-2017-02; QU-2017-03; QU-2018-04; River; rivers; See further details: Parameter metadata description; Silicate; Temperature, water; Water sample; WS; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 573 data points
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  • 8
    Publication Date: 2024-06-28
    Description: This dataset contains methane and nitrous oxide dissolved gas concentration, dissolved methane carbon isotope, and ancillary hydrographic data from research cruises in the North American Arctic Ocean between 2015-2018. Ocean samples for methane and nitrous oxide analysis were collected from Niskin bottles mounted on a CTD rosette. Water was collected into glass serum bottles and allowed to overflow three times before preserving with mercuric chloride and sealing with with butyl rubber stoppers and aluminum crimp seals. Gas concentrations were determined using a purge and trap system coupled to a gas chromatograph/mass spectrometer, following the method of Capelle et al. (2015). Equilibrium dry atmospheric concentrations were 328.25, 329.14, 330.11, and 330.96 ppb for N2O and 1919.64, 1933.67, 1934.92, and 1933.50 ppb for CH4 in 2015, 2016, 2017, and 2018, respectively. Equilibrium dissolved concentrations were calculated from the measured temperature and salinity following Wiesenburg and Guinasso (1979) for CH4 and Weiss and Price (1980) for N2O. Equilibrium concentrations were calculated based on sample temperature and salinity and the atmospheric N2O or CH4 concentrations measured at Barrow, Alaska by the NOAA Earth System Research Laboratory Global Monitoring Division (Dlugokencky et al., 2020a,b), with corrections to local sea level pressure and 100% humidity. Oxygen concentration was determined using an oxygen sensor mounted on the Niskin rosette, calibrated with discrete samples analyzed by Winkler titration. The mixed layer depth was defined based on a potential density difference criterion of 0.125 kg/m³ relative to the density at 5 m depth, using CTD profiles binned to 1 m. The mixed layer depth was set to 5 m as a minimum. For methane δ13C, samples were pre-concentrated through a purge and trap system (Finnigan PreCon Trace Gas Pre-Concentrator) and measured with a Finnigan Delta XP Plus mass spectrometer following the method of Damm et al. (2015).
    Keywords: 101; 105; 108; 111; 115; 126; 129; 131; 176; 177; 180; 2015-006; 2015-007; 2016-016; 2016-017; 2017-011; 2017-093; 2018-063; 2018-081; 301; 304; 312; 314; 322; 323; 325; 333; 343; 344; 405; 408; 420; 421; 424; 426; 428; 430; 432; 434; 437; 470; 472; 474; 476; 478; 480; 482; 5.1; 535; 554; 694; 732; 736; A16; A2; A8; AG5; AMD15_2; AMD15_2_312-1; AMD15_2_314-1; AMD15_2_325-1; AMD15_2_BB2-1; AMD15_2_BB3-1; AMD15_2_CAA1-1; AMD15_2_CAA2-1; AMD15_2_CAA4-1; AMD15_2_CAA5-1; AMD15_2_CAA6-1; AMD15_2_CAA7-1; AMD15_2_VS-1; AMD16_3a; AMD16_3a_405-1; AMD16_3a_408-1; AMD16_3a_420-1; AMD16_3a_421-1; AMD16_3a_424-1; AMD16_3a_426-1; AMD16_3a_428-1; AMD16_3a_430-1; AMD16_3a_432-1; AMD16_3a_434-1; AMD16_3a_437-1; AMD16_3a_470-1; AMD16_3a_472-1; AMD16_3a_474-1; AMD16_3a_476-1; AMD16_3a_478-1; AMD16_3a_480-1; AMD16_3a_482-1; AMD16_3a_535-1; AMD16_3a_554-1; AMD16_3b; AMD16_3b_312-1; AMD16_3b_314-1; AMD16_3b_343-1; AMD16_3b_344-1; AMD17_2; AMD17_2_101-1; AMD17_2_105-1; AMD17_2_108-1; AMD17_2_111-1; AMD17_2_115-1; AMD17_2_126-1; AMD17_2_129-1; AMD17_2_131-1; AMD17_2_176-1; AMD17_2_180-1; AMD17_2_301-1; AMD17_2_304-1; AMD17_2_312-1; AMD17_2_322-1; AMD17_2_323-1; AMD17_2_325-1; AMD17_2_333-1; AMD17_2_5.1-1; AMD17_2_694-1; AMD17_2_732-1; AMD17_2_736-1; AMD17_2_A16-1; AMD17_2_A2-1; AMD17_2_A8-1; AMD17_2_BB1-1; AMD17_2_BB2-1; AMD17_2_BB3-1; AMD17_2_BELLOT-1; AMD17_2_FS2Deep-1; AMD17_2_FS2Shallow-1; AMD17_2_QMG1-1; AMD17_2_QMG2-1; AMD17_2_QMG3-1; AMD17_2_QMG4-1; AMD17_2_QMGM-1; AMD17_2_TS233-1; AMD18_3; AMD18_3_101-3; AMD18_3_115-3; AMD18_3_177-3; AMD18_3_312-3; AMD18_3_322-3; AMD18_3_DFO-9-3; AMD18_3_DiskoFan-3; AMD18_3_Lophelia-3; AMD18_3_NearTrinity-3; AMD18_3_NLSE-07-3; AMD18_3_QMG1-3; AMD18_3_QMG2-3; AMD18_3_QMG3-3; AMD18_3_QMG4-3; AMD18_3_QMGM-3; AMD18_3_ScottInlet0t2-3; AMD18_3_ScottInlet-3; AMD18_3_SWGreenland3-3; AN1702; Arctic; ArcticNet; ArcticNet/ESRF; ArcticNet/The W. Garfield Weston Foundation; Arctic Ocean; BarC-1; BarC-10; BarC-2; BarC-4; BarC-5; BarC-6; BarC-8; BB1; BB2; BB3; BCL-6A; BELLOT; BL1; BL2; BL3; BL4; BL6; BL8; Bottle number; BRS-3; CAA1; CAA2; CAA4; CAA5; CAA6; CAA7; Calculated; Canadian Coast Guard (Sir W. Laurier); Cast number; CB1; CB23a; CB28aa; CB28b; CB31b; CB4; CCGS Amundsen; CTD, Sea-Bird; CTD/Rosette; CTD-RO; DATE/TIME; DBO4.1; DBO4.2; DBO4.2n; DBO4.3; DBO4.3n; DBO4.4; DBO4.4n; DBO4.5; DBO4.5n; DBO4.6; DBO4.6n; DEPTH, water; DFO-9; DiskoFan; Event label; FS2Deep; FS2Shallow; Gas chromatography - Mass spectrometry (GC-MS); GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; International Polar Year (2007-2008); IPY; LATITUDE; LEG 2 GEOTRACES/ARCTICNET; LONGITUDE; Lophelia; Louis S. St-Laurent; LSL1509; LSL1509_AG5-1; LSL1509_BL2-1; LSL1509_BL4-1; LSL1509_BL6-1; LSL1509_CB1-1; LSL1509_CB23a-1; LSL1509_CB28aa-1; LSL1509_CB31b-1; LSL1509_CB4-1; LSL1509_MK1-1; LSL1509_MK2-1; LSL1509_MK3-1; LSL1509_MK4-1; LSL1609; LSL1609_AG5-1; LSL1609_BL1-1; LSL1609_BL2-1; LSL1609_BL3-1; LSL1609_BL4-1; LSL1609_BL6-1; LSL1609_BL8-1; LSL1609_CB28aa-1; LSL1609_MK1-1; LSL1609_MK2-1; LSL1609_MK3-1; LSL1609_MK4-1; LSL1709; LSL1709_AG5-1; LSL1709_BL1-1; LSL1709_BL2-1; LSL1709_BL3-1; LSL1709_BL4-1; LSL1709_BL6-1; LSL1709_BL8-1; LSL1709_CB28aa-1; LSL1709_CB28b-1; LSL1709_MK3-1; LSL1809; LSL1809_AG5-1; LSL1809_BL1-1; LSL1809_BL2-1; LSL1809_BL3-1; LSL1809_BL4-1; LSL1809_BL6-1; LSL1809_BL8-1; LSL1809_CB28aa-1; LSL1809_MK1-1; LSL1809_MK2-1; LSL1809_MK3-1; LSL1809_MK4-1; Marine Biogeochemistry and Surface Exchange of Climate Active Gases; Methane; Methane, dissolved; Methane, dissolved, equilibrium; Methane, standard deviation; Mixed layer depth; MK1; MK2; MK3; MK4; NearTrinity; nitrous oxide; Nitrous oxide, dissolved; Nitrous oxide, dissolved, equilibrium; Nitrous oxide, standard deviation; NLSE-07; ocean; Oxygen; Pressure, water; QMG1; QMG2; QMG3; QMG4; QMGM; rivers; Salinity; Sample ID; ScottInlet; ScottInlet0t2; SEC-1; SEC-3; SEC-5; SEC-7; SEC-8; SLIP-1; SLIP-3; SLIP-4; SLIP-5; Station label; SWGreenland3; SWL1507; SWL1507_BarC-10-1; SWL1507_BarC-2-1; SWL1507_BarC-4-1; SWL1507_BarC-6-1; SWL1507_BarC-8-1; SWL1507_BCL-6A-1; SWL1507_BRS-3-1; SWL1507_DBO4.1-1; SWL1507_DBO4.2-1; SWL1507_DBO4.3-1; SWL1507_DBO4.5-1; SWL1507_SEC-1-1; SWL1507_SEC-3-1; SWL1507_SEC-5-1; SWL1507_SEC-7-1; SWL1507_SLIP-1-1; SWL1507_SLIP-3-1; SWL1507_SLIP-4-1; SWL1507_SLIP-5-1; SWL1507_UTBS-2-1; SWL1507_UTBS-4-1; SWL1507_UTN-1-1; SWL1507_UTN-3-1; SWL1507_UTN-7-1; SWL1607; SWL1607_BCL-6A-1; SWL1607_BRS-3-1; SWL1607_DBO4.1-1; SWL1607_DBO4.3-1; SWL1607_SEC-1-1; SWL1607_SEC-3-1; SWL1607_SEC-5-1; SWL1607_SEC-7-1; SWL1607_SLIP-1-1; SWL1607_SLIP-3-1; SWL1607_SLIP-4-1; SWL1607_SLIP-5-1; SWL1607_UTBS-1-1; SWL1607_UTBS-5-1; SWL1607_UTN-2-1; SWL1607_UTN-4-1; SWL1607_UTN-6-1; SWL1707; SWL1707_BarC-10-1; SWL1707_BarC-1-1; SWL1707_BarC-5-1; SWL1707_BCL-6A-1; SWL1707_BRS-3-1; SWL1707_DBO4.1-1; SWL1707_DBO4.2-1; SWL1707_DBO4.3-1; SWL1707_DBO4.4-1; SWL1707_DBO4.5-1; SWL1707_DBO4.6-1; SWL1707_SEC-1-1; SWL1707_SEC-3-1; SWL1707_SEC-5-1; SWL1707_SEC-7-1; SWL1707_SEC-8-1; SWL1707_SLIP-1-1; SWL1707_SLIP-3-1; SWL1707_SLIP-4-1; SWL1707_SLIP-5-1; SWL1707_UTBS-1-1; SWL1707_UTBS-5-1; SWL1707_UTN-2-1; SWL1707_UTN-4-1; SWL1707_UTN-6-1; SWL1807; SWL1807_BCL-6A-1; SWL1807_BRS-3-1; SWL1807_DBO4.2n-1; SWL1807_DBO4.3n-1; SWL1807_DBO4.4n-1; SWL1807_DBO4.5n-1; SWL1807_DBO4.6n-1; SWL1807_SEC-1-1; SWL1807_SEC-3-1; SWL1807_SEC-5-1; SWL1807_SEC-7-1; SWL1807_SLIP-1-1; SWL1807_SLIP-3-1; SWL1807_SLIP-4-1; SWL1807_SLIP-5-1; SWL1807_UTBS-1-1; SWL1807_UTBS-5-1; SWL1807_UTN-2-1; SWL1807_UTN-4-1; Temperature, water; Thermo Trace GC coupled to ThermoFinnigan DELTAplus XP (GC-C-IRMS); TS233; UTBS-1; UTBS-2; UTBS-4; UTBS-5; UTN-1; UTN-2; UTN-3; UTN-4; UTN-6; UTN-7; VS; δ13C, methane, dissolved; δ13C, methane, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 37056 data points
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  • 9
    Publication Date: 2024-06-28
    Description: This dataset contains methane and nitrous oxide dissolved gas concentration, dissolved methane carbon isotope, and ancillary hydrographic data from research cruises in the North American Arctic Ocean between 2015-2018. Ocean samples for methane and nitrous oxide analysis were collected from Niskin bottles mounted on a CTD rosette. Water was collected into glass serum bottles and allowed to overflow three times before preserving with mercuric chloride and sealing with with butyl rubber stoppers and aluminum crimp seals. Gas concentrations were determined using a purge and trap system coupled to a gas chromatograph/mass spectrometer, following the method of Capelle et al. (2015). Equilibrium dry atmospheric concentrations were 328.25, 329.14, 330.11, and 330.96 ppb for N2O and 1919.64, 1933.67, 1934.92, and 1933.50 ppb for CH4 in 2015, 2016, 2017, and 2018, respectively. Equilibrium dissolved concentrations were calculated from the measured temperature and salinity following Wiesenburg and Guinasso (1979) for CH4 and Weiss and Price (1980) for N2O. Equilibrium concentrations were calculated based on sample temperature and salinity and the atmospheric N2O or CH4 concentrations measured at Barrow, Alaska by the NOAA Earth System Research Laboratory Global Monitoring Division (Dlugokencky et al., 2020a,b), with corrections to local sea level pressure and 100% humidity. Oxygen concentration was determined using an oxygen sensor mounted on the Niskin rosette, calibrated with discrete samples analyzed by Winkler titration. The mixed layer depth was defined based on a potential density difference criterion of 0.125 kg/m³ relative to the density at 5 m depth, using CTD profiles binned to 1 m. The mixed layer depth was set to 5 m as a minimum. The instantaneous gas transfer velocities and fluxes are based on the instantaneous wind speed at the time of sampling. The 30-day weighted gas transfer velocities and fluxes are integrated over the residence time of the gas in the mixed layer, using up to the prior 30 days of observations, following the method of Teeter et al. (2018) as described in the main manuscript of Manning et al. (2022). The 60-day weighted gas transfer velocities and fluxes are integrated over the residence time of the gas in the mixed layer, using the prior 60 days of observations, following the method of Teeter et al. (2018) as described in the main manuscript of Manning et al. (2022). Atmospheric sea level pressure was obtained from the NCEP/NCAR reanalysis product, which is provided by the NOAA-ESRL Physical Sciences Laboratory (https://psl.noaa.gov/data/gridded). Fractional ice cover was obtained from the EUMETSAT Ocean and Sea Ice Satellite Application Facility (https://osi-saf.eumetsat.int). Sea ice concentration product AMSR-2 (identifier OSI-408) was used in 2017–2018 and SSMIS (identifier OSI-401-b) was used in 2015–2016.
    Keywords: 101; 105; 108; 111; 115; 126; 129; 131; 176; 177; 180; 2015-006; 2015-007; 2016-016; 2016-017; 2017-011; 2017-093; 2018-063; 2018-081; 301; 304; 312; 314; 322; 323; 325; 333; 343; 344; 405; 408; 420; 421; 424; 426; 428; 430; 432; 434; 437; 470; 472; 474; 476; 478; 480; 482; 5.1; 535; 554; 694; 732; A16; A2; A8; AG5; AMD15_2; AMD15_2_312-1; AMD15_2_314-1; AMD15_2_325-1; AMD15_2_BB2-1; AMD15_2_BB3-1; AMD15_2_CAA1-1; AMD15_2_CAA2-1; AMD15_2_CAA4-1; AMD15_2_CAA5-1; AMD15_2_CAA6-1; AMD15_2_CAA7-1; AMD15_2_VS-1; AMD16_3a; AMD16_3a_312-1; AMD16_3a_314-1; AMD16_3a_343-1; AMD16_3a_344-1; AMD16_3a_405-1; AMD16_3a_408-1; AMD16_3a_420-1; AMD16_3a_421-1; AMD16_3a_424-1; AMD16_3a_426-1; AMD16_3a_428-1; AMD16_3a_430-1; AMD16_3a_432-1; AMD16_3a_434-1; AMD16_3a_437-1; AMD16_3a_470-1; AMD16_3a_472-1; AMD16_3a_474-1; AMD16_3a_476-1; AMD16_3a_478-1; AMD16_3a_480-1; AMD16_3a_482-1; AMD16_3a_535-1; AMD16_3a_554-1; AMD17_2; AMD17_2_101-1; AMD17_2_105-1; AMD17_2_108-1; AMD17_2_111-1; AMD17_2_115-1; AMD17_2_126-1; AMD17_2_129-1; AMD17_2_131-1; AMD17_2_176-1; AMD17_2_180-1; AMD17_2_301-1; AMD17_2_304-1; AMD17_2_312-1; AMD17_2_322-1; AMD17_2_323-1; AMD17_2_325-1; AMD17_2_333-1; AMD17_2_5.1-1; AMD17_2_694-1; AMD17_2_732-1; AMD17_2_A16-1; AMD17_2_A2-1; AMD17_2_A8-1; AMD17_2_BB1-1; AMD17_2_BB2-1; AMD17_2_BB3-1; AMD17_2_BELLOT-1; AMD17_2_FS2Deep-1; AMD17_2_QMG1-1; AMD17_2_QMG2-1; AMD17_2_QMG3-1; AMD17_2_QMG4-1; AMD17_2_QMGM-1; AMD17_2_TS233-1; AMD18_3; AMD18_3_101-3; AMD18_3_115-3; AMD18_3_177-3; AMD18_3_312-3; AMD18_3_322-3; AMD18_3_DFO-9-3; AMD18_3_DiskoFan-3; AMD18_3_Lophelia-3; AMD18_3_NearTrinity-3; AMD18_3_NLSE-07-3; AMD18_3_QMG1-3; AMD18_3_QMG2-3; AMD18_3_QMG3-3; AMD18_3_QMG4-3; AMD18_3_QMGM-3; AMD18_3_ScottInlet0t2-3; AMD18_3_ScottInlet-3; AMD18_3_SWGreenland3-3; AN1702; Arctic; ArcticNet; ArcticNet/ESRF; Arctic Ocean; BarC-1; BarC-10; BarC-2; BarC-4; BarC-5; BarC-6; BarC-8; BB1; BB2; BB3; BCL-6A; BELLOT; BL1; BL2; BL3; BL4; BL6; BL8; BRS-3; CAA1; CAA2; CAA4; CAA5; CAA6; CAA7; Calculated; Canadian Coast Guard (Sir W. Laurier); CB1; CB23a; CB28aa; CB28b; CB31b; CB4; CCGS Amundsen; CTD, Sea-Bird; CTD/Rosette; CTD-RO; DATE/TIME; DBO4.1; DBO4.2; DBO4.2n; DBO4.3; DBO4.3n; DBO4.4; DBO4.4n; DBO4.5; DBO4.5n; DBO4.6; DBO4.6n; DEPTH, water; DFO-9; DiskoFan; Event label; FS2Deep; Gas chromatography - Mass spectrometry (GC-MS); GEOTRACES; Global marine biogeochemical cycles of trace elements and their isotopes; Ice cover, fractional; International Polar Year (2007-2008); IPY; LATITUDE; LEG 2 GEOTRACES/ARCTICNET; LONGITUDE; Lophelia; Louis S. St-Laurent; LSL1509; LSL1509_AG5-1; LSL1509_BL2-1; LSL1509_BL4-1; LSL1509_BL6-1; LSL1509_CB1-1; LSL1509_CB23a-1; LSL1509_CB28aa-1; LSL1509_CB31b-1; LSL1509_CB4-1; LSL1509_MK1-1; LSL1509_MK2-1; LSL1509_MK3-1; LSL1509_MK4-1; LSL1609; LSL1609_AG5-1; LSL1609_BL1-1; LSL1609_BL2-1; LSL1609_BL3-1; LSL1609_BL4-1; LSL1609_BL6-1; LSL1609_BL8-1; LSL1609_CB28aa-1; LSL1609_MK1-1; LSL1609_MK2-1; LSL1609_MK3-1; LSL1609_MK4-1; LSL1709; LSL1709_AG5-1; LSL1709_BL1-1; LSL1709_BL2-1; LSL1709_BL3-1; LSL1709_BL4-1; LSL1709_BL6-1; LSL1709_BL8-1; LSL1709_CB28aa-1; LSL1709_CB28b-1; LSL1709_MK3-1; LSL1809; LSL1809_AG5-1; LSL1809_BL1-1; LSL1809_BL2-1; LSL1809_BL3-1; LSL1809_BL4-1; LSL1809_BL6-1; LSL1809_BL8-1; LSL1809_CB28aa-1; LSL1809_MK1-1; LSL1809_MK2-1; LSL1809_MK3-1; LSL1809_MK4-1; Marine Biogeochemistry and Surface Exchange of Climate Active Gases; Methane; Methane, dissolved; Methane, dissolved, equilibrium; Methane, dissolved, gas transfer velocity; Methane, flux; Methane, standard deviation; Mixed layer depth; MK1; MK2; MK3; MK4; NearTrinity; nitrous oxide; Nitrous oxide, dissolved; Nitrous oxide, dissolved, equilibrium; Nitrous oxide, dissolved, gas transfer velocity; Nitrous oxide, flux; Nitrous oxide, standard deviation; NLSE-07; ocean; Pressure; Pressure, water; QMG1; QMG2; QMG3; QMG4; QMGM; rivers; Salinity; ScottInlet; ScottInlet0t2; SEC-1; SEC-3; SEC-5; SEC-7; SEC-8; SLIP-1; SLIP-3; SLIP-4; SLIP-5; Station label; SWGreenland3; SWL1507; SWL1507_BarC-10-1; SWL1507_BarC-2-1; SWL1507_BarC-4-1; SWL1507_BarC-6-1; SWL1507_BarC-8-1; SWL1507_BCL-6A-1; SWL1507_BRS-3-1; SWL1507_DBO4.1-1; SWL1507_DBO4.2-1; SWL1507_DBO4.3-1; SWL1507_DBO4.5-1; SWL1507_SEC-1-1; SWL1507_SEC-3-1; SWL1507_SEC-5-1; SWL1507_SEC-7-1; SWL1507_SLIP-1-1; SWL1507_SLIP-3-1; SWL1507_SLIP-4-1; SWL1507_SLIP-5-1; SWL1507_UTBS-2-1; SWL1507_UTBS-4-1; SWL1507_UTN-1-1; SWL1507_UTN-3-1; SWL1507_UTN-7-1; SWL1607; SWL1607_BCL-6A-1; SWL1607_BRS-3-1; SWL1607_DBO4.1-1; SWL1607_DBO4.3-1; SWL1607_SEC-1-1; SWL1607_SEC-3-1; SWL1607_SEC-5-1; SWL1607_SEC-7-1; SWL1607_SLIP-1-1; SWL1607_SLIP-3-1; SWL1607_SLIP-4-1; SWL1607_SLIP-5-1; SWL1607_UTBS-1-1; SWL1607_UTBS-5-1; SWL1607_UTN-2-1; SWL1607_UTN-4-1; SWL1607_UTN-6-1; SWL1707; SWL1707_BarC-10-1; SWL1707_BarC-1-1; SWL1707_BarC-5-1; SWL1707_BCL-6A-1; SWL1707_BRS-3-1; SWL1707_DBO4.1-1; SWL1707_DBO4.2-1; SWL1707_DBO4.3-1; SWL1707_DBO4.4-1; SWL1707_DBO4.5-1; SWL1707_DBO4.6-1; SWL1707_SEC-1-1; SWL1707_SEC-3-1; SWL1707_SEC-5-1; SWL1707_SEC-7-1; SWL1707_SEC-8-1; SWL1707_SLIP-1-1; SWL1707_SLIP-3-1; SWL1707_SLIP-4-1; SWL1707_SLIP-5-1; SWL1707_UTBS-1-1; SWL1707_UTBS-5-1; SWL1707_UTN-2-1; SWL1707_UTN-4-1; SWL1707_UTN-6-1; SWL1807; SWL1807_BCL-6A-1; SWL1807_BRS-3-1; SWL1807_DBO4.2n-1; SWL1807_DBO4.3n-1; SWL1807_DBO4.4n-1; SWL1807_DBO4.5n-1; SWL1807_DBO4.6n-1; SWL1807_SEC-1-1; SWL1807_SEC-3-1; SWL1807_SEC-5-1; SWL1807_SEC-7-1; SWL1807_SLIP-1-1; SWL1807_SLIP-3-1; SWL1807_SLIP-4-1; SWL1807_SLIP-5-1; SWL1807_UTBS-1-1; SWL1807_UTBS-5-1; SWL1807_UTN-2-1; SWL1807_UTN-4-1; Temperature, water; TS233; UTBS-1; UTBS-2; UTBS-4; UTBS-5; UTN-1; UTN-2; UTN-3; UTN-4; UTN-6; UTN-7; VS
    Type: Dataset
    Format: text/tab-separated-values, 6776 data points
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  • 10
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    American Geophysical Union
    In:  EPIC3Journal of Geophysical research: Ocean, American Geophysical Union, 122, pp. 1-18
    Publication Date: 2017-11-12
    Description: We collected Arctic Ocean water column samples for methane (CH4) and nitrous oxide (N2O) analysis on three separate cruises in the summer and fall of 2015, covering a ~10,000 km transect from the Bering Sea to Baffin Bay. This provided a three-dimensional view of CH4 and N2O distributions across contrasting hydrographic environments, from the oligotrophic waters of the deep Canada Basin and Baffin Bay, to the productive shelves of the Bering and Chukchi Seas. Percent saturation relative to atmospheric equilibrium ranged from 30-800% for CH4 and 75-145% for N2O, with the highest concentrations of both gases occurring in the northern Chukchi Sea. Nitrogen cycling in the shelf sediments of the Bering and Chukchi Seas likely constituted the major source of N2O to the water column, and the resulting high N2O concentrations were transported across the Arctic Ocean in eastward-flowing water masses. Methane concentrations were more spatially heterogeneous, reflecting a variety of localized inputs, including likely sources from sedimentary methanogenesis and sea ice processes. Unlike N2O, CH4 was rapidly consumed through microbial oxidation in the water column, as shown by the 13C enrichment of CH4 with decreasing concentrations. For both CH4 and N2O, sea-air fluxes were close to neutral, indicating that our sampling region was neither a major source nor sink of these gases. Our results provide insight into the factors controlling the distribution of CH4 and N2O in the North American Arctic Ocean, and an important baseline data set against which future changes can be assessed.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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