Publication Date:
2014-04-09
Description:
Article For the anti-nucleophilic attack of gold-activated alkynes the linear alignment of ligand, gold and C-C triple bond centroid makes it difficult to achieve interaction between ligand and nucleophile. Here the authors design ligands capable of directing nucleophiles, allowing dramatically reduced catalyst loadings. Nature Communications doi: 10.1038/ncomms4470 Authors: Yanzhao Wang, Zhixun Wang, Yuxue Li, Gongde Wu, Zheng Cao, Liming Zhang
Electronic ISSN:
2041-1723
Topics:
Biology
,
Chemistry and Pharmacology
,
Natural Sciences in General
,
Physics
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