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  • 1
    Series available for loan
    Series available for loan
    Leipzig : Dt. Verl. für Grundstoffindustrie
    Associated volumes
    Call number: S 99.0015(456)
    In: Freiberger Forschungshefte
    Type of Medium: Series available for loan
    Pages: VI, 338 S.
    ISBN: 3342005939
    Series Statement: Freiberger Forschungshefte : C 456 : Geowissenschaften, Lagerstättenlehre
    Language: German
    Location: Lower compact magazine
    Branch Library: GFZ Library
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  • 2
    Publication Date: 2023-07-04
    Description: This study presents new secondary ion mass spectrometry (SIMS) reference materials (RMs) for measuring water contents in nominally anhydrous orthopyroxenes from upper mantle peridotites. The enstatitic reference orthopyroxenes from spinel peridotite xenoliths have Mg#s between 0.83 and 0.86, Al2O3 ranges between 4.02 and 5.56 wt%, and Cr2O3 ranges between 0.21 and 0.69 wt%. Based on Fourier-transform infrared spectroscopy (FTIR) characterizations, the water contents of the eleven reference orthopyroxenes vary from dry to 249 ± 6 µg/g H2O. Using these reference grains, a set of orthopyroxene samples obtained from variably altered abyssal spinel peridotites from the Atlantic and Arctic Ridges as well as from the Izu-Bonin-Mariana forearc region was analyzed by SIMS and FTIR regarding their incorporation of water. The major element composition of the sample orthopyroxenes is typical of spinel peridotites from the upper mantle, characterized by Mg#s between 0.90 and 0.92, Al2O3 between 1.66 and 5.34 wt%, and Cr2O3 between 0.62 and 0.96 wt%. Water contents as measured by SIMS range from 68 ± 7 to 261 ± 11 µg/g H2O and correlate well with Al2O3 contents (r = 0.80) and Cr#s (r. = -0.89). We also describe in detail an optimized strategy, employing both SIMS and FTIR, for quantifying structural water in highly altered samples such as abyssal peridotite. This approach first analyzes individual oriented grains by polarized FTIR, which provides an overview of alteration. Subsequently, the same grain along with others of the same sample is measured using SIMS, thereby gaining information about homogeneity at the hand sample scale, which is key for understanding the geological history of these rocks.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Bavarian Equal Opportunities Sponsorship - Realization Equal Opportunities for Women in Research and Teaching
    Description: Friedrich-Alexander-Universität Erlangen-Nürnberg (1041)
    Keywords: ddc:549 ; FTIR ; Hydrogen ; Nominally anhydrous minerals ; Orthopyroxene ; SIMS ; Spinel peridotite
    Language: English
    Type: doc-type:article
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  • 3
    Publication Date: 2024-05-22
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Erzgebirge ultrahigh‐pressure (UHP) garnet peridotite includes scarce layers of garnet pyroxenite, nodules of garnetite and, very rarely, of eclogite. Peridotite‐hosted eclogite shows the same subalkali‐basaltic bulk rock composition, mineral assemblage and peak conditions as gneiss‐hosted eclogite present in the same UHP unit. Garnetite has considerably more Mg, moderately enhanced Ca and Fe and significantly lower contents of Na, Ti, P, K and Si than eclogite, whereas Al is very similar. In addition, the compatible trace elements (Ni, Co, Cr, V) are elevated and most incompatible elements (Zr, Hf, Y, Sr, Rb and rare Earth elements [REE]) are depleted in garnetite relative to eclogite. In contrast to other large ion lithophile elements (LILEs), Pb (+121%) and Ba (+83%) are strongly enriched. The REE patterns of garnetite are characterized by depletion of light and heavy REE and a medium REE hump indicative of metasomatism, features being absent in eclogite. An exceptional garnetite sample shows an REE distribution similar to that of eclogite. Garnetite is interpreted to have formed from the same, but metasomatically altered, igneous protolith as eclogite. Except for Ba and Pb, the chemical signature of garnetite is explained best by metasomatic changes of its basaltic protolith caused by serpentinization of the host peridotite. Garnetite is chemically similar to basaltic rodingite/metarodingite. Although rodingite is commonly more enriched in Ca, there are also examples with moderately enhanced Ca matching the composition of Erzgebirge garnetite. Limited Ca metasomatism is attributed to the preservation of Ca in peridotite during hydrous alteration. This can be explained by incomplete serpentinization favouring metastable survival of the original clinopyroxene. In this case, most Ca is retained in peridotite and not available for infiltration and metasomatism of the garnetite protolith. This inescapable consequence is supported by the fact that clinopyroxene is part of the garnet peridotite UHP assemblage, which would not be the case if Ca had been removed from the protolith prior to high‐pressure metamorphism. The enrichment of compatible elements in garnetite is attributed to decomposition of peridotitic olivine (Ni, Co) and spinel (Cr, V) during serpentinization. Enrichment of Ba and Pb contrasts the behaviour of other LILEs and is ascribed to dehydration of the serpentinized peridotite (deserpentinization). This requires two separate stages of metasomatism: (1) intense chemical alteration of the basaltic garnetite precursor, together with serpentinization of peridotite at the ocean floor or during incipient subduction; and (2) prograde metamorphism and dehydration of serpentinite during continued subduction, thereby releasing Pb–Ba‐rich fluids that reacted with associated metabasalt. Finally, subduction to >100 km and UHP metamorphism of all lithologies led to formation of garnetite, eclogite and garnet pyroxenite hosted by co‐facial garnet peridotite as observed in the Erzgebirge.〈/p〉
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:552.4 ; Erzgebirge ; garnetite ; rodingitization ; serpentinization ; UHP metamorphism
    Language: English
    Type: doc-type:article
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 110 (1992), S. 226-241 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The metamorphic sequences of the Saxonian Erzgebirge were thoroughly overprinted by a Variscan medium-pressure event under amphibolite facies conditions. However, eclogitic relics documenting an older high-pressure event are widespread. P-T conditions of the eclogite-facies metamorphism systematically decrease, over a distance of 50 km, from about 〉29 kbar/850°C, in the central part, to 20–24 kbar/650°C, in the westernmost part of the Erzgebirge crystalline complex. A distinct gap in P-T conditions exists between the central and the western Erzgebirge coinciding with the fault zone of the Flöha syncline. Therefore, the eclogitebearing sequences are assumed to represent at least two different nappe units. The lower-grade eclogite assemblages in the western Erzgebirge display a continuous metamorphic zonation with a gradual decrease of peak metamorphic temperatures towards the west. Assemblages formed in the stability field of coesite and thus indicating a regional ultra-high pressure metamorphism, are restricted to the central Erzgebirge, where they are widespread in the eclogites, but also present in metaacidic country rocks. The same high-temperature/high-pressure conditions, testifying to a burial of at least 100 km, were independently recorded for the ultramafic garnet pyroxenites associated with the eclogites of the central Erzgebirge. Mineral relics included in the eclogite phases and mineral assemblages formed by retrograde reactions permit reconstruction of the prograde and retrograde P-T paths in the different parts of the Erzgebirge crystalline complex.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract In the Erzgebirge Crystalline Complex, eclogites occur in three different high pressure (HP) units (1, 2 and 3) recording contrasting pressure (P)–temperature (T) conditions. Eclogites from HP-unit 1 experienced peak metamorphic conditions in the coesite stability field at about 33 kbar/850 °C. Commonly, these eclogites from HP-unit 1 are all very similar, with an eclogitic peak assemblage of omphacite–garnet–coesite–K-feldspar, rarely accompanied by kyanite, and omphacites systematically deviating from a stoichiometric composition. In contrast, an eclogite recently found near Blumenau, is mineralogically and geochemically different from the typical eclogites of HP-unit 1. This unusual eclogite reveals the eclogitic equilibrium assemblage omphacite–garnet–coesite–phengite–phlogopite–kyanite, and yields metamorphic peak conditions of 870 °C and 〉29 kbar. There is clear textural evidence of the formation of phlogopite and kyanite under partial consumption of phengite and garnet. Moreover, the omphacite is stoichiometric and contains abundant exsolution lamellae, the thickest of which were identified as quartz by the electron microprobe. The finer lamellae were studied by transmission electron microscopy (TEM). Oligoclase was identified as an exsolution phase. Other lamellae proved to consist of K-white mica, also interpreted as exsolution. Prior to exsolution, the omphacite composition must have been cation-deficient, as that of the other, common HP-unit 1 eclogites. These non-stoichiometric compositions are ascribed to partial substitution by the Ca-Eskola pyroxene component, which calculates to an average of 8 mol% for omphacite in HP-unit 1 eclogites. According to experiments, this substitution becomes significant at P 〉 30 kbar. Exsolution of K-white mica may indicate hydroxyl defects in the original omphacite, also favoured by high pressure. Oligoclase and K-white mica exsolution from Ca-Eskola-rich clinopyroxene has not previously been reported. The omphacite has a disordered C2/c structure; and in just one case very small (a few tens of nanometres) antiphase domains, resulting from the C2/c to P2/n transformation, are present. These features may indicate a brief thermal history and rapid tectonic processes.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Calculated phase equilibria among the minerals sodic amphibole, calcic amphibole, garnet, chloritoid, talc, chlorite, paragonite, margarite, omphacite, plagioclase, carpholite, zoisite/clinozoisite, lawsonite, pyrophyllite, kyanite, sillimanite, quartz and H2O are presented for the model system Na2O-CaO-FeO-MgO-Al2O3-SiO2-H2O (NCFMASH), which is relevant for many greenschist, blueschist, amphibolite and eclogite facies rocks. Using the activity-composition relationships for multicomponent amphiboles constrained by Will and Powell (1992), equilibria containing coexisting calcic and sodic amphiboles could be determined. The blueschist–greenschist transition reaction in the NCFMASH system, for example, is defined by the univariant reaction sodic amphibole + zoisite = calcic amphibole + chlorite + paragonite + plagioclase (+ quartz + H2O) occurring between approximately 420 and 450 °C at 9.5 to 10 kbar. The calculated petrogenetic grid is a valuable tool for reconstructing the PT-evolution of metabasic rocks. This is shown for rocks from the island of Samos, Greece. On the basis of mineral and whole rock analyses, PT-pseudosections were calculated and, together with the observed mineral assemblages and reaction textures, are used to reconstruct PT-paths. For rocks from northern Samos, pseudomorphs after lawsonite preserved in garnet, the assemblage sodic amphibole-garnet-paragonite-chlorite-zoisite-quartz and the retrograde appearance of albitic plagioclase and the formation of calcic amphibole around sodic amphibole constrain a clockwise PT-path that reaches its thermal maximum at some 520 °C and 19 kbar. The derived PT-trajectory indicates cooling during exhumation of the rocks and is similar to paths for rocks from the western part of the Attic-Cycladic crystalline complex. Rocks from eastern Samos indicate lower pressures and are probably related to high-pressure rocks from the Menderes Massif in western Turkey.
    Type of Medium: Electronic Resource
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  • 7
    Publication Date: 2018-02-01
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 8
    Publication Date: 2020-07-13
    Print ISSN: 0263-4929
    Electronic ISSN: 1525-1314
    Topics: Geosciences
    Published by Wiley
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  • 9
    Publication Date: 2015-09-01
    Print ISSN: 0024-4937
    Electronic ISSN: 1872-6143
    Topics: Geosciences
    Published by Elsevier
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  • 10
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