ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Intramolecular charge transfer processes in a series of thetrans-isomers of styryl derivatives of pyridines and quinolines, their hydrochlorides and molecular complexes with BF3 have been studied by electronic and IR spectroscopy. Electron donor groups involved in direct resonance conjugation with the N-oxide group intensify these processes, while electron acceptor nitro groups somewhat weaken them. Protons and BF3 coordinate to the oxygen of the N→O group to form strong 1∶1 complexes, except in the cases of 4-(4-dimethylaminostyryl)quinoline and pyridine N-oxides, in which a second acceptor molecule adds to the amino group.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02311331
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