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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 781-805 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Thermally induced dehydrochlorination is a well-established and prominent degradation mode for vinylidene chloride copolymers. During extrusion, other processes may represent significant degradation pathways. Under shear in air, both oxidative chain-scission and cross-linking are prominent processes for both vinylidene chloride/vinyl chloride and vinylidene chloride/methyl acrylate copolymers. Both processes are dependent upon shear rate and temperature. The shear-stress dependency can be modeled by a kinetic expression that incorporates shear stress into the Arrhenius preexponential factor. Vinylidene chloride/methyl acrylate copolymers appear to be somewhat more susceptible to oxidative chain-scission than are comparable vinylidene chloride/vinyl chloride copolymers, presumably because of a rapid oxidative attack at exposed methyl acrylate units. Shear-induced degradation of these materials in air is characterized by early predominant chain-scission with cross-linking assuming a greater importance as a function of time. Degradation under shear in a nonoxidative environment is a much simpler process - oxidative chain-scission is suppressed and cross-linking is very similar to that observed in air. © 1994 John Wiley & Sons, Inc.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2024-04-08
    Beschreibung: The Observing Air–Sea Interactions Strategy (OASIS) is a new United Nations Decade of Ocean Science for Sustainable Development programme working to develop a practical, integrated approach for observing air–sea interactions globally for improved Earth system (including ecosystem) forecasts, CO2 uptake assessments called for by the Paris Agreement, and invaluable surface ocean information for decision makers. Our “Theory of Change” relies upon leveraged multi-disciplinary activities, partnerships, and capacity strengthening. Recommendations from 〉40 OceanObs’19 community papers and a series of workshops have been consolidated into three interlinked Grand Ideas for creating #1: a globally distributed network of mobile air–sea observing platforms built around an expanded array of long-term time-series stations; #2: a satellite network, with high spatial and temporal resolution, optimized for measuring air–sea fluxes; and #3: improved representation of air–sea coupling in a hierarchy of Earth system models. OASIS activities are organized across five Theme Teams: (1) Observing Network Design & Model Improvement; (2) Partnership & Capacity Strengthening; (3) UN Decade OASIS Actions; (4) Best Practices & Interoperability Experiments; and (5) Findable–Accessible–Interoperable–Reusable (FAIR) models, data, and OASIS products. Stakeholders, including researchers, are actively recruited to participate in Theme Teams to help promote a predicted, safe, clean, healthy, resilient, and productive ocean.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2019-12-13
    Repository-Name: EPIC Alfred Wegener Institut
    Materialart: Conference , notRev
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Publikationsdatum: 2024-06-10
    Beschreibung: The strategic ambition is to develop an operational, comprehensive, and resourced system that delivers priority observations and information to guide mitigation and adaptation responses to climate change, sustains ocean health within a sustainable blue economy, and facilitates informed decision-making for science, business and society. Such a system is envisioned to be co-designed, fit-for-purpose, multidisciplinary, geographically expanded, responsive, and sustainable in time, delivering ocean observations to all nations and users, prioritising societal needs. Transforming ocean observations into accessible information will require integration across disciplines, across national observing systems, along the value chain, and across stakeholders. Innovative technology approaches and a diversified set of actors and approaches will be required for success. The Global Ocean Observing System (GOOS) of IOC UNESCO can provide the implementation framework for Challenge 7 and the UN Ocean Decade provides the opportunity and vehicle for transformation. Five recommendations have been identified to fulfil the strategic ambition of Ocean Decade Challenge 7. Act now on known observational needs. Upgrade and expand ocean observing capacity in poorly-observed areas such as polar regions, island nations and territories, coastal areas of developing nations, coastal systems that are rapidly changing, and the under-observed deep ocean. Thematic priorities for ocean observing by 2030 should focus on key climate risk and adaptation needs, extreme events, coastal services for ocean management, ocean carbon, marine pollution, biogeochemistry, and biodiversity. Adopt new economic thinking. Establish new and sustained financing mechanisms for global ocean observing, including resourcing for Small Island Developing States (SIDS) and Least Developed Countries (LDCs). Use economic models for ocean investment to diversify and accelerate investment in ocean observing and infrastructure from new actors. Partnerships are key. Increase national, regional and global coordination, focusing on co-design and partnerships. Improved coordination that uses the GOOS framework to ensure standards, best practices for a sustainably expanded GOOS. Diversify partnerships across sectors (economic, public, private, and philanthropic) and embrace the abilities and needs of the different stakeholders to co-design, co-develop, and co-deliver observations that translate into the information required by these sectors. Technology and innovation will be a pillar. Integrate and harmonise observations across observing platforms (in situ, satellite, emerging networks). Develop innovative in situ, autonomous and cost-effective technologies to maximise reach, ensuring standardisation and best practices. Technology barriers still need to be lowered to ensure everyone has equitable access to observing technology and has the ability to use these assets. Artificial Intelligence (AI) and Machine Learning (ML) tools will provide user-ready information from integrated observations to democratise information for users. Expanded, capable, and diversified workforce. Expand and diversify the workforce of skilled and trained ocean professionals. Training and capacity development will be critical across the observing ‘ecosystem’ outlined in the Framework for Ocean Observing (FOO), from data collection to data analysis and modelling, and for data use and application.
    Beschreibung: Published
    Beschreibung: Refereed
    Schlagwort(e): Ocean observation ; GOOS ; Global Ocean Observing System ; Ocean observing
    Repository-Name: AquaDocs
    Materialart: Report
    Format: 22pp.
    Standort Signatur Erwartet Verfügbarkeit
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